Single-Ion Magnets with Giant Magnetic Anisotropy and Zero-Field Splitting
M Georgiev, H Chamati - ACS omega, 2022 - ACS Publications
The design of mononuclear molecular nanomagnets exhibiting a huge energy barrier to the
reversal of magnetization have seen a surge of interest during the last few decades due to …
reversal of magnetization have seen a surge of interest during the last few decades due to …
Perspectives on Neutron Scattering in Lanthanide-Based Single-Molecule Magnets and a Case Study of the Tb2(μ-N2) System
Single-molecule magnets (SMMs) based on lanthanide ions display the largest known
blocking temperatures and are the best candidates for molecular magnetic devices …
blocking temperatures and are the best candidates for molecular magnetic devices …
Magnetic excitations in polyoxotungstate-supported lanthanoid single-molecule magnets: an inelastic neutron scattering and ab initio study
Inelastic neutron scattering (INS) has been used to investigate the crystal field (CF) magnetic
excitations of the analogs of the most representative lanthanoid–polyoxometalate single …
excitations of the analogs of the most representative lanthanoid–polyoxometalate single …
Magnetic relaxation of lanthanide-based molecular magnets
Molecular magnets containing lanthanide ions have been receiving an increasing level of
attention during the last years. The applicability of molecular magnets on foreseeable …
attention during the last years. The applicability of molecular magnets on foreseeable …
Contrasting impact of coordination polyhedra and site symmetry on the electronic energy levels in nine-coordinated Eu (III) and Sm (III) crystals structures determined …
SS Mortensen, VRM Nielsen, TJ Sørensen - Dalton Transactions, 2024 - pubs.rsc.org
Lanthanide luminescence is characterised by “forbidden” 4f–4f transitions and a
complicated electronic structure. Our understanding of trivalent lanthanide (III) ion …
complicated electronic structure. Our understanding of trivalent lanthanide (III) ion …
Nine‐coordinated Eu3+ Dipicolinate Compounds: Different Crystal Structures and Luminescence Properties as a Function of pH
SS Mortensen, TJ Sørensen - European Journal of Inorganic …, 2023 - Wiley Online Library
Abstract Two compounds, Na3 [Eu (DPA) 3]⋅ 14H2O and [Eu (DPA)(HDPA)(H2O) 2]⋅
4H2O, were created and the structure determined using single crystal X‐ray diffraction. The …
4H2O, were created and the structure determined using single crystal X‐ray diffraction. The …
Geometry and magnetism of lanthanide compounds
Z Zhu, J Tang - Organometallic Magnets, 2019 - Springer
Lanthanide single molecule magnets (Ln-SMMs) were still been considered as the
exceptionally promising candidates in high-density data storage and quantum calculation …
exceptionally promising candidates in high-density data storage and quantum calculation …
Accurate and unequivocal determination of the crystal-field parameters of lanthanide ions via a multitechnique approach
M Slota, SD Jiang, E Heintze, Y Rechkemmer… - Physical Review B, 2019 - APS
Understanding the crystal field of lanthanide complexes is pivotal for the testing of Stevens
operator equivalents and the development of lanthanide-based molecular magnets. Intense …
operator equivalents and the development of lanthanide-based molecular magnets. Intense …
A six-legged piano stool dysprosium single-molecule magnet
Dysprosium single-molecule magnets (SMMs) with two mutually trans-anionic ligands have
shown large crystal field (CF) splitting, giving record effective energy barriers to magnetic …
shown large crystal field (CF) splitting, giving record effective energy barriers to magnetic …
Impact of Symmetry and Donor Set on the Electronic Energy Levels in Nine-coordinated Eu (III) and Sm (III) Crystals Structures Determined from Single Crystal …
SS Mortensen, VRM Nielsen, TJ Sørensen - 2024 - chemrxiv.org
Lanthanide luminescence is characterised by “forbidden” 4f-4f transitions and a complicated
electronic structure. Our understanding of trivalent lanthanide (III) ions luminescence is …
electronic structure. Our understanding of trivalent lanthanide (III) ions luminescence is …