Rearrangement reactions, one of the most significant transformations in organic chemistry,
play an irreplaceable role in improving synthetic efficiency and molecular complexity …

Conspectus Alkenes are ubiquitous in natural products and are extensively used as
synthetic feedstocks in multiple fields including organic synthesis, medicinal chemistry, and …

From the viewpoint of synthetic accessibility and functional group compatibility, photoredox-
catalyzed sulfur dioxide insertion strategy enables in situ generation of functionalized …

Compounds having cyclic molecular frameworks are highly regarded for their abundance
and diverse utilities. In particular, medium-sized carbocycles and heterocycles exist in a …

In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …

Medium-sized rings have much promise in medicinal chemistry, but are difficult to make
using direct cyclisation methods. In this minireview, we highlight the value of ring expansion …

Recent protocols and reactions for catalytic radical perfluoroalkylations will be described.
The production of perfluoroalkyl radicals (RF= C n F2 n+ 1, n≥ 2), which effect both addition …

Transition‐metal‐free radical α‐perfluoroalkylation with the accompanying vicinal β‐
alkenylation of unactivated alkenes is presented. These radical cascades proceed by means …

Radical-mediated controllable difunctionalization of alkenes provides a powerful tool for the
manipulation of olefins and has become a hot topic recently. In general, however, the scope …

Radical‐mediated difunctionalization of alkenes is a powerful tactic for olefin utilization.
However, the transformation of unactivated alkenes still remains a formidable challenge …