Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

In recent years, the silver‐catalyzed and silver‐promoted isocyanide reactions have
attracted much attention, due to its efficiency in the formation of diverse new bonds and good …

An I2-mediated [3+ 2] annulation of methyl-azaarenes with alkyl 2-isocyanoacetates or
amino acid ester hydrochlorides has been demonstrated. This strategy involves CN bond …

Herein, we report that under mild and transition-metal-free conditions an unprecedented and
practical SN2′ reaction of Morita–Baylis–Hillman adducts with isocyanoacetates takes …

Atropisomers possessing additional stereogenic centres have found wide applications in
various fields; however, the development of catalytic asymmetric reactions for their …

An organocatalytic asymmetric synthesis of directly linked benzothiazole‐dihydroimidazoles
with two adjacent tertiary‐quaternary stereocenters through a Mannich‐type reaction of …

We report here a Cu‐catalyzed enantioselective intramolecular oxidation of cyclic
diaryliodoniums. With readily available cyclic diaryliodoniums as building blocks, diversified …

Axially chiral biaryl scaffolds are important in pharmaceuticals, natural products, and
asymmetric synthesis. Atroposelective ring‐opening of configurationally labile biaryl …

The first palladium‐catalyzed allylation of isocyanoacetates with vinyl aziridines has been
developed. The reaction conditions were suitable for a variety of α‐aryl isocyanoacetates as …

Catalytic asymmetric 1, 3-dipolar cycloaddition reactions of activated isocyanides with
various 2π dipolarophiles have been intensively studied, affording a wide range of …