摘要纳米颗粒通常具有优异的催化性能, 但由于其内在的异质性, 宏观水平的表征难以确定单个
纳米颗粒可靠的构效关系和潜在的催化反应机制. 单分子荧光成像技术具有单分子灵敏度 …

Charge transfer at solid interfaces and ensuing interfacial electric fields on the order of 109
V/m are ubiquitous in nanostructures and hybrid materials. Here, we address how intrinsic …

Measuring the catalytical activities of single catalysts in the case of high turnover frequency
(TOF, realistic conditions) is highly desirable to accurately evaluate the functional …

With the ever-increasing demands for energy and declining reserves of fossil fuels, efficient
use of fossil fuels and energy extraction from alternative raw materials are critical to the …

Electrooxidation of carbon monoxide (CO) and small oxygenate molecules is of great
interest for direct alcohol fuel cell (DAFC) and electroorganic synthesis. Herein, we …

Alcohol amination via hydrogen borrowing is an established method for the clean and
simple alkylation of amines with alcohols, which are stable and available in bulk; it also does …

The rapid pace of industrialization has led to a multitude of detrimental environmental
consequences, including water pollution and global warming. Consequently, there is an …

The movement of molecules (ie diffusion) within angstrom-scale pores of porous materials
such as metal-organic frameworks (MOFs) and zeolites is influenced by multiple complex …

Chemical reactions feature complex mechanisms with molecules undergoing multiple
transformations going from starting materials to products. To better understand chemical …

A chemical species can be considered as confined when it is localized in a small space and
experiences geometrical constraints caused by the environment. Confinement takes place in …