Surface premelting of water ice

B Slater, A Michaelides - Nature Reviews Chemistry, 2019 - nature.com
Frozen water has a quasi-liquid layer at its surface that exists even well below the bulk
melting temperature; the formation of this layer is termed premelting. The nature of the …

Ice-nucleating and antifreeze proteins recognize ice through a diversity of anchored clathrate and ice-like motifs

A Hudait, N Odendahl, Y Qiu, F Paesani… - Journal of the …, 2018 - ACS Publications
Cold-adapted organisms produce antifreeze and ice-nucleating proteins to prevent and
promote ice formation. The crystal structure of hyperactive bacterial antifreeze protein (AFP) …

Hydrogen-bonding and hydrophobic groups contribute equally to the binding of hyperactive antifreeze and ice-nucleating proteins to ice

A Hudait, Y Qiu, N Odendahl… - Journal of the American …, 2019 - ACS Publications
Hyperactive insect antifreeze proteins and bacterial ice-nucleating proteins are arguably the
most potent ice-binding molecules in nature. These highly effective proteins bind ice through …

[HTML][HTML] Polymorphic selectivity in crystal nucleation

Y Gui, C Huang, C Shi, T Stelzer… - The Journal of chemical …, 2022 - pubs.aip.org
Crystal nucleation rates have been measured in the supercooled melts of two richly
polymorphic glass-forming liquids: ROY and nifedipine (NIF). ROY or 5-methyl-2-[(2 …

[HTML][HTML] Fundamental aspects of ice nucleation via pore condensation and freezing including Laplace pressure and growth into macroscopic ice

C Marcolli - Atmospheric Chemistry and Physics, 2020 - acp.copernicus.org
Pore condensation and freezing (PCF) is an ice nucleation mechanism that explains ice
formation at low ice supersaturation. It assumes that liquid water condenses in pores of solid …

Pre-critical fluctuations and what they disclose about heterogeneous crystal nucleation

M Fitzner, GC Sosso, F Pietrucci, S Pipolo… - Nature …, 2017 - nature.com
Heterogeneous crystal nucleation is ubiquitous in nature and at the heart of many industrial
applications. At the molecular scale, however, major gaps in understanding this …

[HTML][HTML] Pre-ordering of interfacial water in the pathway of heterogeneous ice nucleation does not lead to a two-step crystallization mechanism

L Lupi, B Peters, V Molinero - The Journal of chemical physics, 2016 - pubs.aip.org
According to Classical Nucleation Theory (CNT), the transition from liquid to crystal occurs in
a single activated step with a transition state controlled by the size of the crystal embryo. This …

Why is it so difficult to identify the onset of ice premelting?

Y Qiu, V Molinero - The journal of physical chemistry letters, 2018 - ACS Publications
Premelting of ice at temperatures below 0° C is of fundamental importance for environmental
processes. Various experimental techniques have been used to investigate the temperature …

[HTML][HTML] Homogeneous ice nucleation rates for mW and TIP4P/ICE models through Lattice Mold calculations

I Sanchez-Burgos, AR Tejedor, C Vega… - The Journal of …, 2022 - pubs.aip.org
Freezing of water is the most common liquid-to-crystal phase transition on Earth; however,
despite its critical implications on climate change and cryopreservation among other …

Is ice nucleation by organic crystals nonclassical? An assessment of the monolayer hypothesis of ice nucleation

AK Metya, V Molinero - Journal of the American Chemical Society, 2021 - ACS Publications
Potent ice nucleating organic crystals display an increase in nucleation efficiency with
pressure and memory effect after pressurization that set them apart from inorganic …