Metal-N-Heterocyclic Carbene Chemistry Directed toward Metallosupramolecular Synthesis and Beyond

S Bai, YF Han - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus As versatile, modular, and strongly coordinating moieties in organometallic
compounds, N-heterocyclic carbenes (NHCs) have led to numerous breakthroughs in …

Construction of olefinic coordination polymer single crystal platforms: precise organic synthesis, in situ exploration of reaction mechanisms and beyond

Q Zhang, Y Wang, P Braunstein, JP Lang - Chemical Society Reviews, 2024 - pubs.rsc.org
Olefin [2+ 2] photocycloaddition reactions based on coordination-bond templates provide
numerous advantages for the selective synthesis of cyclobutane compounds. This review …

Phase Transition‐Promoted Rapid Photomechanical Motions of Single Crystals of a Triene Coordination Polymer

C Cao, XR Xue, QY Li, MJ Zhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Molecular crystals with the ability to transform light energy into macroscopic mechanical
motions are a promising class of materials with potential applications in actuating and …

Soluble and processable single-crystalline cationic polymers

Y Liu, XR Guan, DC Wang, JF Stoddart… - Journal of the American …, 2023 - ACS Publications
Single-crystal-to-single-crystal (SCSC) polymerization offers an effective protocol for the
environmentally friendly preparation of polymer single crystals (PSCs) with extremely high …

A Recyclable Supramolecular Photocatalyst for the Chemoselective [2+ 2] Photocycloaddition of Chalcones in Water

Y Fu, Y Xia, Y Xu, X Ye, S Xie, Y Wu… - ACS Sustainable …, 2023 - ACS Publications
Herein, we disclose a recyclable supramolecular photocatalytic system that enables efficient
intermolecular homo-and cross-[2+ 2] photocycloadditions of chalcones in an aqueous …

Hierarchical self-assembly of a radical naphthalenediimide-based N-heterocyclic carbene-Au (i) macrocycle

C Wang, QW Zhu, JG Yu, X Li, H Li, LY Sun… - Inorganic Chemistry …, 2023 - pubs.rsc.org
Here, we show that a naphthalenediimide skeleton can facilitate the hierarchical assembly
of a derived metal N-heterocyclic carbene (NHC) macrocycle into diverse supramolecular …

A cationic radical lanthanide organic tetrahedron with remarkable coordination enhanced radical stability

Z Zhu, S Hu, Z Liu, L Zhou, C Tian, Q Sun - Chinese Chemical Letters, 2024 - Elsevier
Rare–earth supramolecular compounds, such as lanthanide organic polyhedrons (LOPs),
are of particular interest due to their many possible applications in various fields. Here we …

Coordination Polymer-Mediated Molecular Surgery for Precise Interconversion of Dicyclobutane Compounds

N Wang, RP Yan, YS Xiong, Y Mi, FL Hu, Y Ge… - Inorganic …, 2022 - ACS Publications
A Cd (II)-based coordination polymer {[Cd2 (5-F-1, 3-bpeb) 2 (FBA) 4]· H2O} n (CP 1) was
obtained from Cd (II) salt, 5-fluoro-1, 3-bis [2-(4-pyridyl) ethenyl] benzene (5-F-1, 3-bpeb) …

The Use of Photocycloaddition Reactions to Drive Mechanical Motions Resembling Humanoid Movements

Y Wang, Q Zhang, Q Liu, BF Abrahams… - Angewandte Chemie … - Wiley Online Library
With the aim of producing a photomechanical material for incorporation in soft microrobots, a
one‐dimensional diene coordination polymer (CP)[Cd (F‐bpeb)(3‐CBA) 2] n (CP1, F‐bpeb …

Coordination Site Selective Occupation Strategy for Tuning the Photosalient Effects of Photoactive Cd Complexes

S Zhao, N Wang, DJ Young, Y Mi, F Hu - Chemistry–An Asian Journal - Wiley Online Library
The application of photo responsive crystals to useful actuation demands a rational design
to elicit controllable movement. The [2+ 2] photocycloaddition reaction triggers mechanical …