Controlling mineral morphologies and structures in biological and synthetic systems

FC Meldrum, H Cölfen - Chemical reviews, 2008 - ACS Publications
The unique and frequently beautiful morphologies that characterize many biominerals have
long been a source of fascination. While research began by looking first at individual …

In situ techniques in biomimetic mineralization studies of calcium carbonate

A Dey, NAJM Sommerdijk - Chemical Society Reviews, 2010 - pubs.rsc.org
The often astonishing material properties of crystalline biominerals are generally related to
the hierarchical assembly of specifically interacting organic and inorganic components. To …

Nucleation of metastable aragonite CaCO3 in seawater

W Sun, S Jayaraman, W Chen… - Proceedings of the …, 2015 - National Acad Sciences
Predicting the conditions in which a compound adopts a metastable structure when it
crystallizes out of solution is an unsolved and fundamental problem in materials synthesis …

Biomimetic mineralization

AW Xu, Y Ma, H Cölfen - Journal of Materials Chemistry, 2007 - pubs.rsc.org
Biomimetic mineralization is a powerful approach for the synthesis of advanced materials
with complex shape, hierarchical organization and controlled size, shape and polymorph …

Sea urchin tooth design: an “all‐calcite” polycrystalline reinforced fiber composite for grinding rocks

Y Ma, SR Cohen, L Addadi, S Weiner - Advanced Materials, 2008 - Wiley Online Library
Many sea urchins obtain their food by scraping rocky surfaces. They do this using teeth
composed almost entirely of magnesium-bearing calcite. Paradoxically, the substrates …

Hydrogels coupled with self-assembled monolayers: an in vitro matrix to study calcite biomineralization

H Li, LA Estroff - Journal of the American Chemical Society, 2007 - ACS Publications
This paper describes the control of the nucleation and growth of calcite crystals by a matrix
composed of an agarose hydrogel on top of a carboxylate-terminated self-assembled …

Biomimetic synthesis of calcite films by a polymer-induced liquid-precursor (PILP) process: 1. Influence and incorporation of magnesium

X Cheng, PL Varona, MJ Olszta, LB Gower - Journal of Crystal Growth, 2007 - Elsevier
Magnesium-bearing calcium carbonate films have been synthesized via a polymer-induced
liquid-precursor (PILP) mineralization process. A variety of morphological features of …

Aragonite crystallization in a sulfate-rich hypersaline wetland under dry Mediterranean climate (Laguna Honda, eastern Guadalquivir basin, S Spain)

A Medina-Ruiz, J Jiménez-Millán, I Abad… - Science of the Total …, 2024 - Elsevier
This research investigates the influence of water composition, the presence of seasonal
algal mats, detrital inputs and the activity of microorganisms on the crystallization of …

Amino acid assisted incorporation of dye molecules within calcite crystals

B Marzec, DC Green, MA Holden… - Angewandte Chemie …, 2018 - Wiley Online Library
Biomineralisation processes invariably occur in the presence of multiple organic additives,
which act in combination to give exceptional control over structures and properties …

Structural Development of Mercaptophenol Self-Assembled Monolayers and the Overlying Mineral Phase during Templated CaCO3 Crystallization from a Transient …

JRI Lee, TYJ Han, TM Willey, D Wang… - Journal of the …, 2007 - ACS Publications
Formation of biomineral structures is increasingly attributed to directed growth of a mineral
phase from an amorphous precursor on an organic matrix. While many in vitro studies have …