Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Atomically precise graphene nanoribbons: interplay of structural and electronic properties

RSK Houtsma, J de la Rie, M Stöhr - Chemical Society Reviews, 2021 - pubs.rsc.org
Graphene nanoribbons hold great promise for future applications in nanoelectronic devices,
as they may combine the excellent electronic properties of graphene with the opening of an …

[HTML][HTML] Frontiers of on-surface synthesis: From principles to applications

Q Shen, HY Gao, H Fuchs - Nano Today, 2017 - Elsevier
On-surface synthesis is the bottom-up construction of covalent bonds between molecular
building blocks, which has been greatly developed during the past decade. Dozens of …

[HTML][HTML] Electronic, structural and chemical effects of charge-transfer at organic/inorganic interfaces

R Otero, ALV de Parga, JM Gallego - Surface Science Reports, 2017 - Elsevier
During the last decade, interest on the growth and self-assembly of organic molecular
species on solid surfaces spread over the scientific community, largely motivated by the …

The Role of Metal Adatoms in a Surface‐Assisted Cyclodehydrogenation Reaction on a Gold Surface

J Björk, C Sánchez‐Sánchez, Q Chen… - Angewandte Chemie …, 2022 - Wiley Online Library
Dehydrogenation reactions are key steps in many metal‐catalyzed chemical processes and
in the on‐surface synthesis of atomically precise nanomaterials. The principal role of the …

Chemisorption-induced formation of biphenylene dimer on Ag (111)

Z Zeng, D Guo, T Wang, Q Chen, A Matěj… - Journal of the …, 2021 - ACS Publications
We report an example that demonstrates the clear interdependence between surface-
supported reactions and molecular-adsorption configurations. Two biphenyl-based …

Mechanistic picture and kinetic analysis of surface-confined Ullmann polymerization

M Di Giovannantonio, M Tomellini… - Journal of the …, 2016 - ACS Publications
Surface-confined polymerization via Ullmann coupling is a promising route to create one-
and two-dimensional covalent π-conjugated structures, including the bottom-up growth of …

Benzo-fused periacenes or double helicenes? Different cyclodehydrogenation pathways on surface and in solution

Q Zhong, Y Hu, K Niu, H Zhang, B Yang… - Journal of the …, 2019 - ACS Publications
Controlling the regioselectivity of C–H activation in unimolecular reactions is of great
significance for the rational synthesis of functional graphene nanostructures, which are …

Real-space imaging of a phenyl group migration reaction on metal surfaces

Z Ruan, B Li, J Lu, L Gao, S Sun, Y Zhang… - Nature …, 2023 - nature.com
The explorations to extend present chemical synthetic methods are of great importance to
simplify synthetic routes of chemical species. Additionally, understanding the chemical …

Surface-confined alternating copolymerization with molecular precision by stoichiometric control

L Xing, J Li, Y Bai, Y Lin, L Xiao, C Li, D Zhao… - Nature …, 2024 - nature.com
Keen desires for artificial mimicry of biological polymers and property improvement of
synthesized ones have triggered intensive explorations for sequence-controlled …