Do interfacial layers in thin films act as an independent layer within thin films?
The thermodynamic behavior of thin Poly (vinyl methyl ether)(PVME) films including the
irreversible adsorbed layer on the substrate is investigated. In the first step, the growth …
irreversible adsorbed layer on the substrate is investigated. In the first step, the growth …
Proximity to graphene dramatically alters polymer dynamics
Proximity to graphene has an extraordinary effect on the dynamics of entangled chains, as
evidenced by strong slowing of thermally stimulated fluctuations at the surface of a thin …
evidenced by strong slowing of thermally stimulated fluctuations at the surface of a thin …
[HTML][HTML] Experimental study of substrate roughness on the local glass transition of polystyrene
Numerous computer simulations have shown that local dynamics associated with the glass
transition can be slower next to rough interfaces compared with smooth interfaces. Even …
transition can be slower next to rough interfaces compared with smooth interfaces. Even …
In Situ Real-Time Atomic Force Microscopy Observation of the Surface Mobility on Each Domain of a Polystyrene-b-poly(methyl methacrylate) Film at High …
J Kumaki - Langmuir, 2024 - ACS Publications
The surface chain movements within the microdomains of a polystyrene-b-poly (methyl
methacrylate)(PS-b-PMMA) and corresponding homopolymer films were observed via in situ …
methacrylate)(PS-b-PMMA) and corresponding homopolymer films were observed via in situ …
[HTML][HTML] Stabilization of polystyrene thin films by introduction of a functional end group
S Shimomura, M Inutsuka, K Tajima, M Nabika… - Polymer …, 2016 - nature.com
The thin film stabilities of ω-N-(3-(dimethylamino) propyl) propylamide-terminated
polystyrene (PS-N) and its blends with conventional polystyrene (PS-H) supported on silicon …
polystyrene (PS-N) and its blends with conventional polystyrene (PS-H) supported on silicon …
Constructing a Comprehensive Nanopattern Library through Morphological Transitions of Block Copolymer Surface Micelles via Direct Solvent Immersion
S Bae, DH Kim, SY Kim - Small, 2024 - Wiley Online Library
This study establishes a comprehensive library of nanopatterns achievable by a single block
copolymer (BCP), ranging from spheres to complex structures like split micelles, flower‐like …
copolymer (BCP), ranging from spheres to complex structures like split micelles, flower‐like …
Irreversible Physisorption of PS-b-PMMA Copolymers on Substrates for Balanced Interfacial Interactions as a Versatile Surface Modification
We present a direct approach to fabricating the perfect neutral layer for block copolymer
(BCP) self-assembled thin films. An irreversible physisorption of polystyrene-b-poly (methyl …
(BCP) self-assembled thin films. An irreversible physisorption of polystyrene-b-poly (methyl …
Dynamics of polylactic acid under ultrafine nanoconfinement: The collective interface effect and the spatial gradient
Polymers under nanoconfinement can exhibit large alterations in dynamics from their bulk
values due to an interface effect. However, understanding the interface effect remains a …
values due to an interface effect. However, understanding the interface effect remains a …
Unraveling the dynamics of nanoscopically confined PVME in thin films of a miscible PVME/PS blend
S Madkour, P Szymoniak, J Radnik… - ACS applied materials …, 2017 - ACS Publications
Broadband dielectric spectroscopy (BDS) was employed to investigate the glassy dynamics
of thin films (7–200 nm) of a poly (vinyl methyl ether)(PVME)/polystyrene (PS) blend (50: 50 …
of thin films (7–200 nm) of a poly (vinyl methyl ether)(PVME)/polystyrene (PS) blend (50: 50 …
Recent Advancements in Experimental Methods for Investigating Irreversible Chain Adsorption at Polymer-Solid Interfaces
Y Wu, Q Wang, H Sun, S Wang, Z Han, J Chen, Z Wu… - Polymer, 2024 - Elsevier
Polymer-solid interfaces are crucial in determining the properties and performance of a
diverse array of materials, ranging from polymer-based thin film devices to polymer …
diverse array of materials, ranging from polymer-based thin film devices to polymer …