Near-infrared metal agents assisting precision medicine: from strategic design to bioimaging and therapeutic applications

C Li, Y Pang, Y Xu, M Lu, L Tu, Q Li… - Chemical Society …, 2023 - pubs.rsc.org
Metal agents have made incredible strides in preclinical research and clinical applications in
recent years, but their short emission/absorption wavelengths continue to be a barrier to …

When near-infrared fluorescence meets supramolecular coordination complexes: Challenges and opportunities of metallacycles/metallacages in precision …

Y Xu, Y Dou, Q Li, H Ye, Y Li, S Qiu, X Xiong, J Li… - Coordination Chemistry …, 2023 - Elsevier
In the past decade, the metallacycles/metallacages have attracted unremitting interest in
biomedical fields, yet visual tracking of their in vivo delivery, targeting ability, biodistribution …

[HTML][HTML] Supramolecular photodynamic agents for simultaneous oxidation of NADH and generation of superoxide radical

KX Teng, LY Niu, N Xie, QZ Yang - Nature Communications, 2022 - nature.com
Given that Type-I photosensitizers (PSs) have hypoxia tolerance, developing general
approaches to prepare Type-I PSs is of great importance, but remains a challenge. Here, we …

Engineered bacteria labeled with iridium (III) photosensitizers for enhanced photodynamic immunotherapy of solid tumors

W Lin, Y Liu, J Wang, Z Zhao, K Lu, H Meng… - Angewandte …, 2023 - Wiley Online Library
Despite metal‐based photosensitizers showing great potential in photodynamic therapy for
tumor treatment, the application of the photosensitizers is intrinsically limited by their poor …

Recent progress in metal-organic cages for biomedical application: Highlighted research during 2018–2023

YP Wang, Y Zhang, XH Duan, JJ Mao, M Pan… - Coordination Chemistry …, 2024 - Elsevier
Metal-organic cages (MOCs) are a class of widely used nanosize supramolecular
architectures with specific geometric shapes and confined cavities, constructed from the …

Porphyrin-based multicomponent metallacage: host–guest complexation toward photooxidation-triggered reversible encapsulation and release

Z Zhang, L Ma, F Fang, Y Hou, C Lu, C Mu, Y Zhang… - JACS Au, 2022 - ACS Publications
The development of supramolecular hosts with effective host–guest properties is crucial for
their applications. Herein, we report the preparation of a porphyrin-based metallacage …

Double Cation− π Directed Two-Dimensional Metallacycle-Based Hierarchical Self-Assemblies for Dual-Mode Catalysis

W Chen, Z Chen, Y Chi, W Tian - Journal of the American …, 2023 - ACS Publications
Hierarchical self-assembly of Pt (II) metallacycles for the construction of functional materials
has received considerable research interest, owing to their potential to meet increasing …

A double-cavity nor-seco-cucurbit [10] uril-based fluorescent probe for detection of ClO-and its application in cell imaging

R Cen, M Liu, H Xiao, HP Yang, LX Chen, Q Li… - Sensors and Actuators B …, 2023 - Elsevier
A supramolecular fluorescent probe based on double-cavity nor-seco-cucurbit [10] uril (ns-Q
[10]) was constructed using the non-covalent host-guest interactions between ns-Q [10] and …

[HTML][HTML] Strategies to address key challenges of metallacycle/metallacage-based supramolecular coordination complexes in biomedical applications

D Xu, Y Li, S Yin, F Huang - Chemical Society Reviews, 2024 - pubs.rsc.org
Owing to their capacity for dynamically linking two or more functional molecules,
supramolecular coordination complexes (SCCs), exemplified by two-dimensional (2D) …

Light‐Responsive Supramolecular Liquid‐Crystalline Metallacycle for Orthogonal Multimode Photopatterning

YX Hu, X Hao, D Wang, ZC Zhang… - Angewandte Chemie …, 2024 - Wiley Online Library
The development of multimode photopatterning systems based on supramolecular
coordination complexes (SCCs) is considerably attractive in supramolecular chemistry and …