The thermostable four-coordinate divalent lanthanide (Ln) bis-amidinate complexes [Ln
(Piso) 2](Ln= Tb, Dy; Piso={(NDipp) 2CtBu}, Dipp= C6H3iPr2-2, 6) were prepared by the …

The isolation of formally two-coordinate lanthanide (Ln) complexes is synthetically
challenging, due to predominantly ionic Ln bonding regimes favoring high coordination …

Understanding metal-metal bonding involving f-block elements has been a challenging goal
in chemistry. Here we report a series of mixed-valence di-metallofullerenes, ThDy@ C2 n (2 …

High-yield syntheses of the lanthanide dinitrogen complexes [(Cp2tttM) 2 (μ-1, 2-N2)](1M,
M= Gd, Tb, Dy; Cpttt= 1, 2, 4-C5 t Bu3H2), in which the [N2] 2–ligands solely adopt the rare …

A conjunction of Single‐Molecule Magnet (SMM) behavior and luminescence thermometry
is an emerging research line aiming at contactless read‐out of temperature in future SMM …

Owing to their potential applications in areas such as information storage, molecular
spintronics, and quantum computing among others; the field of single molecule magnets …

Isolated dysprosocenium cations,[Dy (CpR) 2]+(CpR= substituted cyclopentadienyl), have
recently been shown to exhibit superior single-molecule magnet (SMM) properties over …

High‐performance and air‐stable single‐molecule magnets (SMMs) can offer great
convenience for the fabrication of information storage devices. However, the controversial …

Lanthanide ions have attracted great interest owing to their optical and magnetic properties.
Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years …

Dy (III) bis-cyclopentadienyl (Cp) sandwich compounds exhibit extremely strong single-ion
magnetic anisotropy which imbues them with magnetic memory effects such as magnetic …