Enantioselective functionalization of racemic alkyl halides is an efficient strategy to
assemble complex chiral molecules, but remains one of the biggest challenges in organic …

An iridium‐catalyzed remote site‐switchable hydroarylation of alkenes was reported,
delivering the products functionalized at the subterminal methylene and terminal methyl …

Ligand‐controlled regiodivergent cobalt‐catalyzed ring‐opening dihydroboration of
arylidenecyclopropanes is developed to access synthetically versatile skipped diboronates …

Catalytic isomerization of alkenes is a powerful tool for the construction of complex
synthetically valuable molecules due to their redox-neutral, atom-and step-economical …

The Ni-catalyzed highly selective diborylative cyclization of 1, 6-enynes with diboron reagent
has been developed. When pinB-Bdan was used, multiple types of boron-containing …

Defect-engineered metal–organic frameworks (DEMOFs) are emerging advanced materials.
The construction of DEMOFs is of great significance; however, DEMOF-based catalysis …

Asymmetric hydroboration is among the most powerful and straightforward methods to
construct chiral organoboron compounds, which are extensively used in natural products …

A Rh (I) complex [κ2 (P, N)‐{P (Oquin) 3} RhCl (PPh3)](1) bearing the P, N ligand tris (8‐
quinolinyl) phosphite, P (Oquin) 3, has been synthesized and structurally characterized. The …

金属链迁移偶联策略为远程C (sp3)—H 键直接官能团化提供了高效的新方法,
可以快速实现从简单烯烃底物到复杂官能化产物的转化(Scheme 1A)[1]. 但是目前的研究大多 …

A Rh‐catalyzed asymmetric hydroboration of dialkyl ketone‐derived silyl enol ethers with
HBpin has been developed using a commercially available catalyst and ligand ([RhCl (cod)] …