In this contribution, we provide a comprehensive overview of acyclic twisted amides,
covering the literature since 1993 (the year of the first recognized report on acyclic twisted …

Conspectus Nitrogen heterocycles are present in approximately 60% of drugs, with
nonplanar heterocycles incorporating stereogenic centers being of considerable interest to …

Novel-substituted pyrrolidine derivatives are widely used in drugs and bioactive molecules.
The efficient synthesis of these valuable skeletons, especially enantiopure derivatives, is still …

There have been significant advancements in radical-mediated reactions through covalent-
based organocatalysis. Here, we present the generation of iminyl and amidyl radicals via N …

The high demand for new and efficient routes toward synthesis of nitrogen-containing
heterocyclic scaffolds has inspired organic chemists to discover several methodologies over …

It is attractive to develop a durable and renewable carbon nitride-based photocatalytic
system for compelling photocatalytic organic synthesis, but remains a huge challenge. In this …

A highly enantioselective dearomative [3+ 2] annulation of quinolines, isoquinolines, and
pyridines with donor–acceptor aminocyclopropanes was achieved. With C 1-symmetric …

Herein, we report a copper (I)-catalyzed asymmetric 1, 3-dipolar cycloaddition of azomethine
ylides and 1, 3-enynes, which provides a series of chiral poly-substituted pyrrolidines in high …

Indolizidine alkaloids are chemical constituents isolated from various marine and terrestrial
plants and animals, including but not limited to trees, fungi, ants, and frogs, with a myriad of …

We report here a catalytic method for the modular ring expansion of cyclic aliphatic alcohols.
In this work, proton-coupled electron transfer activation of an allylic alcohol substrate affords …