Calix [4] pyrrole and its derivatives are key members of the supramolecular Parthenon along
with other well-recognized receptor systems, such as crown ethers, cyclodextrins (CDs) …

The vibrational characteristics of 28 different boronic acid, boroxine anhydride, and boronate
ester species have been systematically investigated using a combination of experimental …

Modular frameworks featuring well‐defined pore structures in microscale domains establish
tailor‐made porous materials. For open molecular solids however, maintaining long‐range …

Chromatography techniques based on chiral stationary phases are widely used for the
separation of enantiomers. In particular, gas chromatography has developed rapidly in …

Porous shape‐persistent organic cages have become the object of interest in recent years
because they are soluble and thus processable from solution. A variety of cages can be …

Generating sets of trial structures that sample the configurational space of crystal packing
possibilities is an essential step in the process of ab initio crystal structure prediction (CSP) …

Porous organic cages (POCs) emerge as a new category of crystalline extended solids—
assembled by discrete organic molecules—featuring cage-shaped architectures and …

Imine synthesis has enjoyed a long history as the dynamic covalent reaction of choice for the
construction of purely covalent molecular architectures. In organic solvents, the formation of …

Recently, porous organic crystals (POC) based on macrocycles have shown exceptional
sorption and separation properties. Yet, the impact of guest presence inside a macrocycle …

A dynamic nucleophilic aromatic substitution of tetrazines (SNTz) is presented herein. It
combines all the advantages of dynamic covalent chemistry with the versatility of the …