Dissipative formation of covalent basket cages

VW Liyana Gunawardana, TJ Finnegan… - Angewandte …, 2022 - Wiley Online Library
Living systems use chemical fuels to transiently assemble functional structures. As a step
toward constructing abiotic mimics of such structures, we herein describe dissipative …

Transformation of a [4+ 6] salicylbisimine cage to chemically robust amide cages

AS Bhat, SM Elbert, WS Zhang, F Rominger… - Angewandte …, 2019 - Wiley Online Library
In recent years, interest in shape‐persistent organic cage compounds has steadily
increased, not least because dynamic covalent bond formation enables such structures to …

Dynamic covalent assembly of tribenzotriquinacenes into molecular cubes

S Klotzbach, T Scherpf, F Beuerle - Chemical Communications, 2014 - pubs.rsc.org
Molecular cubes constructed from catechol-functionalized tribenzotriquinacenes and 1, 4-
phenylene diboronic acids were synthesized in a one-pot procedure by crosslinking 20 …

Encapsulating metal nanocatalysts within porous organic hosts

X Yang, Q Xu - Trends in Chemistry, 2020 - cell.com
The encapsulation of metal nanoparticles (MNPs) inside porous organic hosts (POHs), such
as metal-organic frameworks, covalent organic frameworks, organic molecular cages, and …

Trapping white phosphorus within a purely organic molecular container produced by imine condensation

T Jiao, L Chen, D Yang, X Li, G Wu… - Angewandte Chemie …, 2017 - Wiley Online Library
Three tetrahedral organic cages have been obtained by condensing a triamino linker with a
set of three ostensibly analogous triformyl precursors. Despite the large number of imine …

Encapsulation of a Porous Organic Cage into the Pores of a Metal–Organic Framework for Enhanced CO2 Separation

J Liang, A Nuhnen, S Millan, H Breitzke… - Angewandte Chemie …, 2020 - Wiley Online Library
We present a facile approach to encapsulate functional porous organic cages (POCs) into a
robust MOF by an incipient‐wetness impregnation method. Porous cucurbit [6] uril (CB6) …

Solvatomorphism Influence of Porous Organic Cage on C2H2/CO2 Separation

W Wang, K Su, ESM El-Sayed, M Yang… - ACS Applied Materials …, 2021 - ACS Publications
Porous organic molecular (POM) materials can exhibit solvatomorphs via altering their
crystallographic packing in the solid state, but investigating real gas mixture separation by …

[HTML][HTML] Assembled molecular face-rotating polyhedra to transfer chirality from two to three dimensions

X Wang, Y Wang, H Yang, H Fang, R Chen… - Nature …, 2016 - nature.com
In nature, protein subunits on the capsids of many icosahedral viruses form rotational
patterns, and mathematicians also incorporate asymmetric patterns into faces of polyhedra …

A coordinative solubilizer method to fabricate soft porous materials from insoluble metal–organic polyhedra

A Carné‐Sánchez, GA Craig, P Larpent… - Angewandte …, 2019 - Wiley Online Library
Porous molecular cages have a characteristic processability arising from their solubility,
which allows their incorporation into porous materials. Attaining solubility often requires …

Self-assembly of nanometer-sized boroxine cages from diboronic acids

K Ono, K Johmoto, N Yasuda, H Uekusa… - Journal of the …, 2015 - ACS Publications
By use of the reversible trimerization of boronic acids, the series of boroxine cages 3-mer, 6-
mer, and 12-mer were constructed from rationally designed diboronic acids whose bond …