Phase-transfer catalysis (PTC) is one of the most powerful catalytic manifolds for asymmetric
synthesis. Chiral cationic or anionic PTC strategies have enabled a variety of …

Access to regioselective monofluorinated alkenes concurrently from fluoroalkenylating
building blocks such as gem-difluorocyclopropanes represents a powerful synthetic tool and …

Herein, we have successfully developed a convergent paired electrolysis strategy for the
defluorinative thiolation process utilizing thiols and gem-difluoroalkenes as precursors. This …

Recent advances in dearomatization through halofunctionalization reactions are
summarized in this Minireview. Two general categories of strategies are currently employed …

Modulating the reaction selectivity is highly attractive and pivotal to the rational design of
synthetic regimes. The defluorinative functionalization of gem-difluorocyclopropanes …

This study presents a novel method for the regioselective coupling of gem-difluorinated
cyclopropanes with gem-diborylmethane, utilizing a Pd-catalyst system. This innovative …

The new millennium has witnessed the rapid development of synthetic organofluorine
chemistry all over the world, and chemists in China have made significant contributions in …

In 2015, we reported a photochemical method for directed C–C bond cleavage/radical
fluorination of relatively unstrained cyclic acetals using Selectfluor and catalytic 9 …

Fluorinated carbohydrates have found many applications in the glycosciences. Typically,
these contain fluorination at a single position. There are not many applications involving …

Herein, we present an overview of recent advances in the electrochemical halogenation of
organic compounds. Halogen-containing compounds are essential building blocks for post …