Abstract Standard [NiFe]-hydrogenase from Desulfovibrio vulgaris Miyazaki F (DvMF-H 2
ase) catalyzes the uptake and production of hydrogen (H 2) and is a promising biocatalyst …

Hydrogenases are enzymes that can potentially be used in bioelectrical devices or for
biological hydrogen production, the most studied of which are the [NiFe] type. Most [NiFe] …

Ralstonia eutropha H16 is a chemolithoautotrophic bacterium with O2-tolerant hydrogenase
(Hyds) enzymes. Hyds are expressed in the presence of gas mixtures (H2, O2, CO2) or …

[FeFe]-Hydrogenases catalyze the evolution and oxidation of hydrogen using a
characteristic cofactor, termed the H-cluster. This comprises an all cysteine coordinated [4Fe …

Background The chemolithoautotrophic β-proteobacterium Ralstonia eutropha H16
(Cupriavidus necator) is one of the most studied model organisms for growth on H 2 and CO …

The Desulfitobacterium genus comprises anaerobic Gram-positive bacteria, of which the
majority are facultative organohalide respirers. We here present the genomes of eight …

Hydrogen is a clean, renewable energy source, that when combined with oxygen, produces
heat and electricity with only water vapor as a biproduct. Furthermore, it has the highest …

The advancements of quantum chemical methods and computer power allow detailed
mechanistic investigations of metalloenzymes. In particular, both quantum chemical cluster …

Isobutanol (IBT) can be used as a 100% replacement for gasoline in existing automobile
engines, has> 90% of the energy density of gasoline and is compatible with established fuel …

This article summarizes the development of a range of organometallic, biomimetic
analogues of [NiFe] hydrogenases and their employment in a new generation of H2‐O2 fuel …