Pentacoordinate iron dicarbonyls,(NS) Fe (CO) 2P (NS= 2-amidothiophenylate, P= PCy3 (4),
PPh3,(5), and PACHTUNGTRENNUNG (OEt) 3 (6)) were prepared as potential biomimetics …

Carbamyl phosphate (CP) is well-known as an essential intermediate of pyrimidine and
arginine/urea biosynthesis. Chemically, CP can be easily synthesized from dihydrogen …

The genetic context, phylogeny, and biochemistry of a gene flanking the H2-forming
methylene-H4-methanopterin dehydrogenase gene (hmdA), here designated hmdB …

Hydrogenases reversibly catalyze the production of molecular hydrogen. Current interest in
these enzymes is focused on understanding the catalysis, since this may prove useful for …

The organometallic active sites in [NiFe]‐and [FeFe] H2ases are sensitive to oxygen in
varying degrees. The microorganisms that utilize these enzymes for their hydrogen …

Hydrogenases catalyze the reversible oxidation of H2, which is crucial for the anaerobic
metabolism of microorganisms. They attract growing interest in connection with H2‐based …

The complete remineralization of organic matter in anoxic environments relies on
communities of microorganisms that ferment organic acids and alcohols to CH4. This is …

Three half-sandwiched iron (II) monocarbonyl cationic complexes (1+− 3+) containing a
azadiphoshine ligand (PNP, L 1–3) and an iodide as the counter anion,[Fe (II) Cp (CO)(L 1 …

Three half‐sandwich iron (II) complexes,[Fe (η5‐Cp)(cis‐CO) 2X](X−= Cl−, Br−, I−), were
synthesized and characterized. The kinetics of the CO‐releasing behaviour of these …

As a remarkable structural feature of hydrogenase active sites,[NiFe]-hydrogenases harbor
one carbonyl and two cyano ligands, where HypE and HypF are involved in the biosynthesis …