Recent progress in non-native nucleic acid modifications

LK McKenzie, R El-Khoury, JD Thorpe… - Chemical Society …, 2021 - pubs.rsc.org
While Nature harnesses RNA and DNA to store, read and write genetic information, the
inherent programmability, synthetic accessibility and wide functionality of these nucleic acids …

Gold(I)-Catalyzed Glycosylation with Glycosyl o-Alkynylbenzoates as Donors

B Yu - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Naturally occurring glycans and glycoconjugates have extremely diverse
structures and biological functions. Syntheses of these molecules and their artificial mimics …

Gold catalysis in total synthesis—an update

M Rudolph, ASK Hashmi - Chemical Society Reviews, 2012 - pubs.rsc.org
Gold catalysis in total synthesis—an update - Chemical Society Reviews (RSC Publishing)
DOI:10.1039/C1CS15279C Royal Society of Chemistry View PDF VersionPrevious ArticleNext …

O-Glycosylation methods in the total synthesis of complex natural glycosides

Y Yang, X Zhang, B Yu - Natural product reports, 2015 - pubs.rsc.org
Covering: 1994–2015 The total syntheses of 33 complex natural O-glycosides, such as the
glycosides of macrocyclic lactones/lactams, enediynes, angucyclines, and anthracyclines …

[HTML][HTML] Efficient and versatile formation of glycosidic bonds via catalytic strain-release glycosylation with glycosyl ortho−2,2-dimethoxycarbonylcyclopropylbenzoate …

H Ding, J Lyu, XL Zhang, X Xiao, XW Liu - Nature Communications, 2023 - nature.com
Catalytic glycosylation is a vital transformation in synthetic carbohydrate chemistry due to its
ability to expediate the large-scale oligosaccharide synthesis for glycobiology studies with …

Mechanistic Insights into the Gold(I)-Catalyzed Activation of Glycosyl ortho-Alkynylbenzoates for Glycosidation

Y Tang, J Li, Y Zhu, Y Li, B Yu - Journal of the American Chemical …, 2013 - ACS Publications
Anomerization, which involves cleavage and formation of the anomeric C–O bond, is of
fundamental importance in the carbohydrate chemistry. Herein, the unexpected gold (I) …

Gold-catalyzed glycosylation in the synthesis of complex carbohydrate-containing natural products

W Li, B Yu - Chemical Society Reviews, 2018 - pubs.rsc.org
The methodological developments in gold (I)-and gold (III)-catalyzed glycosylation reactions
are fully surveyed, which exploit the special alkynophilicity or the Lewis acidity of the gold …

Synthesis of N‐Glycosides by Silver‐Assisted Gold Catalysis

S Chakraborty, B Mishra, P Kumar Das… - Angewandte Chemie …, 2023 - Wiley Online Library
The synthesis of N‐glycosides from stable glycosyl donors in a catalytic fashion is still
challenging, though they exist ubiquitously in DNA, RNA, glycoproteins, and other biological …

Assembly of naturally occurring glycosides, evolved tactics, and glycosylation methods

B Yu, J Sun, X Yang - Accounts of chemical research, 2012 - ACS Publications
Glycosylation of proteins and lipids is critical to many life processes. Secondary metabolites
(or natural products), such as flavonoids, steroids, triterpenes, and antibiotics, are also …

Recent advances in transition metal-catalyzed glycosylation

MJ McKay, HM Nguyen - ACS catalysis, 2012 - ACS Publications
Having access to mild and operationally simple techniques for attaining carbohydrate
targets will be necessary to facilitate advancement in biological, medicinal, and …