Cobaltaelectro-Catalyzed C–H Annulation with Allenes for Atropochiral and P-Stereogenic Compounds: Late-Stage Diversification and Continuous Flow Scale-Up

Y Lin, T von Münchow, L Ackermann - ACS catalysis, 2023 - ACS Publications
The 3d metallaelectro-catalyzed C–H activation has been identified as an increasingly
viable strategy to access valuable organic molecules in a resource-economic fashion under …

Redox-neutral C–H annulation strategies for the synthesis of heterocycles via high-valent Cp* Co (iii) catalysis

N Bhaduri, AB Pawar - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
A variety of biologically active molecules, pharmaceuticals, and natural products consist of a
nitrogen-containing heterocyclic backbone. The majority of them are isoquinolones, indoles …

Intermolecular Redox-Neutral Carboamination of C–C Multiple Bonds Initiated by Transition-Metal-Catalyzed C–H Activation

Z Zeng, H Gao, Z Zhou, W Yi - ACS Catalysis, 2022 - ACS Publications
Carboamination of readily available feedstock-like alkenes, alkynes, and allenes has proven
to be an efficient and powerful tool for the synthesis of diverse and valuable amine …

Pd-catalyzed regioselective rollover dual C–H annulation cascade: facile approach to phenanthrene derivatives

MN Kumar, V Suresh, A Nagireddy… - Chemical …, 2023 - pubs.rsc.org
Annulations of unsaturated systems through C–H activation represent a powerful tool for
producing multicyclic scaffolds. Having coordinating centers in both annulation partners (a …

Synthesis of condensed tetra-and polycyclic nitrogen heterocycles with a five-membered azacyclic core induced by ionic palladium catalysts

Á Molnár - Coordination Chemistry Reviews, 2024 - Elsevier
This review focuses on recent results with respect to the use of varied ionic palladium
preparations in the synthesis of tetra-and polycyclic heterocycles bearing a five-membered …

Recent Advancement in Palladium-Catalyzed C–C Bond Activation of Strained Ring Systems: Three-and Four-Membered Carbocycles as Prominent C3/C4 Building …

T Nanda, M Fastheem, A Linda, BV Pati… - ACS …, 2022 - ACS Publications
In recent years, transition metal-catalyzed strong C–C bond activation has significantly
attracted the attention of synthetic chemists. This protocol enables simultaneous and direct …

A palladium catalyzed asymmetric desymmetrization approach to enantioenriched 1, 3-disubstituted isoindolines

DH Dethe, V Kumar, M Shukla - Chemical Science, 2023 - pubs.rsc.org
Herein, we report the first palladium/MPAA catalyzed enantioselective C–H activation/[4+ 1]
annulation of diarylmethyltriflamide and olefins to construct chiral cis-1, 3-disubstituted …

Theoretical Investigations of Palladium‐Catalyzed [3+2] Annulation via Benzylic and meta C−H Bond Activation

R Yoshimoto, A Taborosi, Q He, Y Ano… - Chemistry–An Asian …, 2023 - Wiley Online Library
The palladium‐catalyzed reaction of aromatic amides with maleimides results in the
formation of a double C− H bond activation product, which occurs at both the benzylic and …

Rh (iii)-catalyzed substrate-dependent oxidative (spiro) annulation of isoquinolones with diazonaphthoquinones: selective access to new spirocyclic and oxepine …

S Guo, Z Zhang, Y Zhu, Z Wei, X Zhang… - Organic Chemistry …, 2022 - pubs.rsc.org
Reported herein is a practical and selective assembly of novel isoquinolone-containing
spirocyclic and oxepine-fused polycyclic skeletons through a rhodium (III)-catalyzed …

Palladium-Catalyzed [3 + 2] Annulation of ortho-Substituted Iodoarenes with Maleimides via a Consecutive Double Heck-type Strategy

J Naveen, G Satyanarayana - The Journal of Organic Chemistry, 2023 - ACS Publications
Herein, we report an efficient [3+ 2] annulation of ortho-substituted iodoarenes with
maleimides via a palladium-catalyzed consecutive double Heck-type strategy, leading to …