Gas-phase reactions of isoprene and its major oxidation products
Isoprene carries approximately half of the flux of non-methane volatile organic carbon
emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and …
emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and …
Multiphase chemistry at the atmosphere–biosphere interface influencing climate and public health in the anthropocene
U Pöschl, M Shiraiwa - Chemical reviews, 2015 - ACS Publications
Multiphase chemistry plays a vital role in the Earth system, climate, and health. Chemical
reactions, mass transport, and phase transitions between gases, liquids, and solids are …
reactions, mass transport, and phase transitions between gases, liquids, and solids are …
Atmospheric chemistry of Criegee intermediates: Unimolecular reactions and reactions with water
Criegee intermediates are produced in the ozonolysis of unsaturated hydrocarbons in the
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
Criegee intermediates and their impacts on the troposphere
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
Direct Measurements of Conformer-Dependent Reactivity of the Criegee Intermediate CH3CHOO
Although carbonyl oxides,“Criegee intermediates,” have long been implicated in
tropospheric oxidation, there have been few direct measurements of their kinetics, and only …
tropospheric oxidation, there have been few direct measurements of their kinetics, and only …
A large and ubiquitous source of atmospheric formic acid
Formic acid (HCOOH) is one of the most abundant acids in the atmosphere, with an
important influence on precipitation chemistry and acidity. Here we employ a chemical …
important influence on precipitation chemistry and acidity. Here we employ a chemical …
The physical chemistry of Criegee intermediates in the gas phase
DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene
TB Nguyen, GS Tyndall, JD Crounse… - Physical Chemistry …, 2016 - pubs.rsc.org
We use a large laboratory, modeling, and field dataset to investigate the isoprene+ O3
reaction, with the goal of better understanding the fates of the C1 and C4 Criegee …
reaction, with the goal of better understanding the fates of the C1 and C4 Criegee …
Rate coefficients of C1 and C2 Criegee intermediate reactions with formic and acetic acid near the collision limit: direct kinetics measurements and atmospheric …
Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI)
CH2OO and CH3CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and …
CH2OO and CH3CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and …
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII–Criegee intermediates
RA Cox, M Ammann, JN Crowley… - Atmospheric …, 2020 - acp.copernicus.org
This article, the seventh in the series, presents kinetic and photochemical data sheets
evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It …
evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It …