[HTML][HTML] Catalysts for selective hydrogenation of acetylene: A review

K Xie, K Xu, M Liu, X Song, S Xu, H Si - Materials Today Catalysis, 2023 - Elsevier
Ethylene is a crucial industrial feedstock in the petrochemical sector. However, the presence
of a small amount of acetylene impurities in ethylene products will directly affect the next …

Advances in selective electrocatalytic hydrogenation of alkynes to alkenes

Z Liu, L Zhang, Z Ren, J Zhang - Chemistry–A European …, 2023 - Wiley Online Library
Selective electrochemical hydrogenation of alkynes to alkenes under ambient conditions is
a promising alternative to the traditional energy‐intensive and high‐cost thermocatalytic …

Enriching Pt3 ensemble with isolated 3-fold hollow site by crystal-phase engineering of Pt3Fe single-nanoparticle for acetylene hydrogenation

D Zhou, G Zhang, Y Li, S Liu, S Han, Y Zhou… - Chemical Engineering …, 2023 - Elsevier
Tuning the crystal-phase of bimetallic particles enables a precise control of catalytically
active sites but is experimentally challenged by the averaging ensemble effects that are …

Electrocatalytic semihydrogenation of terminal alkynes using ligand-based transfer of protons and electrons

ME Czaikowski, SW Anferov, AP Tascher… - Journal of the …, 2024 - ACS Publications
Alkyne semihydrogenation is a broadly important transformation in chemical synthesis.
Here, we introduce an electrochemical method for the selective semihydrogenation of …

Highly selective low-temperature acetylene semihydrogenation guided by multiscale machine learning

L Chen, XT Li, S Ma, YF Hu, C Shang, ZP Liu - ACS Catalysis, 2022 - ACS Publications
Catalytic hydrogenation is the key measure to remove traces of acetylene in ethylene in the
petroleum industry. Herein we report a highly selective and stable nanocatalyst, Pd1Ag3 …

Enhancing Electrocatalytic Semihydrogenation of Alkynes via Weakening Alkene Adsorption over Electron-Depleted Cu Nanowires

D Luo, Z Xie, S Chen, T Yang, Y Guo, Y Liu… - ACS Nanoscience …, 2024 - ACS Publications
Electrochemical semihydrogenation (ESH) of alkynes to alkenes is an appealing technique
for producing pharmaceutical precursors and polymer monomers, while also preventing …

Synthetic Strategies of Supported Pd-Based Bimetallic Catalysts for Selective Semi-Hydrogenation of Acetylene: A Review and Perspectives

X Cao, BWL Jang, J Hu, L Wang, S Zhang - Molecules, 2023 - mdpi.com
Selective semi-hydrogenation of acetylene is an extremely important reaction from both
industrial and theoretical perspectives. Palladium, due to its unique chemical and physical …

Selective photocatalytic semihydrogenation of alkynols to alkenols on Pd–C3N4 nanosheets under ambient conditions

Z Ren, L Zhang, J Li, J Bu, W Ma, Z Zhao, Z Liu… - Journal of Colloid and …, 2024 - Elsevier
Selective hydrogenation of alkynols to alkenols is an essential process for producing fine
and intermediate chemicals. Currently, thermocatalytic alkynol hydrogenation faces several …

Direct synthesis of a disinfectant with fresh scent of green plants by semi-hydrogenation of alkynol on Pd single-atom catalysts

Y Jiang, X Yu, Y Ji, X Jiang, Y Guo, T Li, L Gao, R Lang… - Nano Research, 2024 - Springer
Alcohol-based disinfectants have protected people in the coronavirus disease 2019 (COVID-
19) pandemic, but olfactory stimuli of ethanol may evoke unpleasant memories associated …

Impact of Pd single-site coordination structure on catalytic performance for semihydrogenation of acetylene

Y Zeng, M Xia, F Gao, C Zhou, X Cheng, L Liu, L Jiao… - Nano Research, 2024 - Springer
Semihydrogenation of trace acetylene in an ethylene gas stream is a vital step for the
industrial production of polyethylene, in which Pd single-site catalysts (SSCs) have great …