A borylidene–phosphorane, the lightest phosphoranylidene, which is stabilized by an N‐
heterocyclic carbene ligand, was synthesized and fully characterized. Experimental electron …

The first C5‐protonated abnormal N‐heterocyclic carbene (aNHC), PhC {N (2, 6‐iPr2C6H3)}
2CHC:(4) is readily accessible by C4‐deprotonation of [ArC {N (2, 6‐iPr2C6H3)} 2CHCH] X …

This study reports the synthesis and single-crystal X-ray crystallographic, NMR
spectroscopic, and magnetic characterization of a series of sodium ferrates using bis …

We report the isolation of free picolyl-functionalized N-heterocyclic carbenes (NHCs), which
serve as versatile precursors to access low coordinate iron and cobalt complexes. The …

Tri‐organyl and tricoordinate N‐heterocyclic carbene (NHC) Zn–NHC alkyl cations [(nNHC)
2Zn‐Me]+(nNHC= C2‐bonded‐IMes/‐IDipp; 3+ and 4+; IMes= 1, 3‐bis (2, 4, 6 …

The preparation and characterization of a NHC-coordinated (NHC= N-heterocyclic carbene)
ferrous phenyl complex [(IPr2Me2) 2FePh2](1; IPr2Me2= 1, 3-diisopropyl-4, 5 …

The salt elimination reactions of (IPr2Me2) 2FeCl2 (IPr2Me2= 1, 3-diisopropyl-4, 5-
dimethylimidazol-2-ylidene) with the corresponding aryl Grignard reagents afford [(IPr2Me2) …

The thermal properties of a series of monomeric copper (I) hexamethyldisilazide complexes
supported by N-heterocyclic and acyclic diamino carbenes were evaluated to study the …

Twisted boron‐based biradicals featuring unsaturated C2R2 (R= Et, Me) bridges and
stabilization by cyclic (alkyl)(amino) carbenes (CAACs) were recently prepared. These …

The binding constants of several monodentate Lewis bases (L) having different donor atoms
[L= tetrahydrofuran (THF), tetrahydrothiophene (THT), pyridine, 4-(dimethylamino) pyridine …