Studies on Three-Coordinate [Co{N(SiMe3)2}2L] Complexes, L = N-Heterocyclic Carbene
A Massard, P Braunstein, AA Danopoulos… - …, 2015 - ACS Publications
A series of three-coordinate N-heterocyclic carbene bis (trimethylsilyl) amide complexes of
cobalt,[Co {N (SiMe3) 2} 2 (NHC)](NHC= N, N′-diarylimidazolin-2-ylidene, aryl= 2, 6 …
cobalt,[Co {N (SiMe3) 2} 2 (NHC)](NHC= N, N′-diarylimidazolin-2-ylidene, aryl= 2, 6 …
Normal-to-abnormal rearrangement of an N-heterocyclic carbene with a silylene transition metal complex
RS Ghadwal, D Rottschäfer, DM Andrada… - Dalton …, 2017 - pubs.rsc.org
The synthesis and characterization of the N-heterocyclic carbene (NHC) stabilized
dichlorosilylene Group 6 metal complexes {(IPr) SiCl2} W (CO) 5 (3-W),{(IPr) SiCl2} 2Cr (CO) …
dichlorosilylene Group 6 metal complexes {(IPr) SiCl2} W (CO) 5 (3-W),{(IPr) SiCl2} 2Cr (CO) …
Application of three-legged piano-stool cyclopentadienyl-N-heterocyclic carbene iron (II) complexes as in situ catalysts for the transfer hydrogenation of ketones
A one pot system has been developed based on nine related 1, 3-dialkylated imidazolium
salts for the in situ generation of N-heterocyclic carbene iron (II) complexes in which the …
salts for the in situ generation of N-heterocyclic carbene iron (II) complexes in which the …
Double donation in trigonal planar iron–carbodiphosphorane complexes–a concise study on their spectroscopic and electronic properties
NJH Kneusels, JE Münzer, K Flosdorf, D Jiang… - Dalton …, 2020 - pubs.rsc.org
We present the syntheses of trigonal planar coordinated Fe (II) carbodiphosphorane (CDPR)
complexes, starting from iron (II)-bis (trimethylsilylamide)[Fe {N (SiMe3) 2} 2] and …
complexes, starting from iron (II)-bis (trimethylsilylamide)[Fe {N (SiMe3) 2} 2] and …
Linear and T-shaped iron (I) complexes supported by N-heterocyclic carbene ligands: Synthesis and structure characterization
Z Ouyang, J Du, L Wang, JL Kneebone… - Inorganic …, 2015 - ACS Publications
The use of the N-heterocyclic carbene (NHC) ligands 1, 3-bis (2′, 6′-diethylphenyl)-4, 5-
(CH2) 4-imidazol-2-ylidene (cyIDep), 1, 3-bis (2′, 6′-diethylphenyl)-imidazolin-2-ylidene …
(CH2) 4-imidazol-2-ylidene (cyIDep), 1, 3-bis (2′, 6′-diethylphenyl)-imidazolin-2-ylidene …
Abnormal-NHC palladium (II) complexes: Rational synthesis, structural elucidation, and catalytic activity
D Rottschäfer, CJ Schürmann, JH Lamm… - …, 2016 - ACS Publications
Reaction of a C2-arylated imidazolium iodide (IPrPh) I (1)(IPrPh= 1, 3-bis (2, 6-
diisopropylphenyl)-2-phenyl-imidazolium) with PdCl2 in the presence of Ag2O affords …
diisopropylphenyl)-2-phenyl-imidazolium) with PdCl2 in the presence of Ag2O affords …
Synthesis of carbamoylphosphates from isocyanates catalyzed by rare-earth-metal alkyl complexes with a silicon-linked diarylamido ligand
X Zhu, D Guo, Y Zhang, Y Wei, S Zhou, M Xu… - …, 2020 - ACS Publications
Neutral rare-earth-metal monoalkyl complexes and anionic rare-earth-metal dialkyl
complexes with a silicon-linked diarylamido ligand were synthesized and characterized, and …
complexes with a silicon-linked diarylamido ligand were synthesized and characterized, and …
A Two-Coordinate iron (II) imido complex with NHC ligation: Synthesis, characterization, and its diversified reactivity of nitrene transfer and C–H bond activation
J Cheng, J Liu, X Leng, T Lohmiller… - Inorganic …, 2019 - ACS Publications
Iron terminal imido species are typically implicated as reaction intermediates in iron-
catalyzed transformations. While a large body of work has been devoted to mid-and high …
catalyzed transformations. While a large body of work has been devoted to mid-and high …
Carbene rearrangements in three-coordinate N-heterocyclic carbene complexes of cobalt (II) bis (trimethylsilyl) amide
BM Day, K Pal, T Pugh, J Tuck, RA Layfield - Inorganic Chemistry, 2014 - ACS Publications
The synthesis and molecular structures of the cobalt (II) N-heterocyclic carbene (NHC)
complexes [(NHC) Co {N (SiMe3) 2} 2], where NHC= 1, 3-bis (diisopropylphenyl) …
complexes [(NHC) Co {N (SiMe3) 2} 2], where NHC= 1, 3-bis (diisopropylphenyl) …
Experimental and theoretical insights into the electronic properties of anionic N-heterocyclic dicarbenes through the rational synthesis of their transition metal …
AA Grineva, OA Filippov, Y Canac, JB Sortais… - Inorganic …, 2021 - ACS Publications
The lithiation of the NHC ligand backbone in Cp (CO) 2Mn (IMes) followed by
transmetalation on the C4 carbenic position with Cp (CO) 2FeI led to the heterobimetallic …
transmetalation on the C4 carbenic position with Cp (CO) 2FeI led to the heterobimetallic …