Reaction of dimesityliron (II)(Fe2 (mes) 4) with the N-heterocyclic carbenes 1, 3-bis (2, 6-
diisopropylphenyl)-imidazol-2-ylidene (IPr) and 1, 3-bis (2, 6-dimethylphenyl) …

The effect of annelation and carbonylation on the electronic and ligating properties of N-
heterocyclic carbenes (NHCs) has been studied quantum chemically. The thermodynamic …

Two silyl donor containing N-heterocyclic carbene iron (II) complexes,[(CSi) Fe
(IMes′)](CSi= bidentate silyl donor containing N-heterocyclic carbene ligand, IMes …

Abstract Typified by LiTMP and TMPMgCl. LiCl,(TMP= 2, 2, 6, 6‐tetramethylpiperidide), s‐
block metal amides have found widespread applications in arene deprotonative metalation …

N-heterocyclic carbene (NHC) ligands are intensively used in transition-metal-catalyzed
reactions. Their bond-activation reactions, however, are much less understood. We now …

The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi)
complex of the iron (II) amide [Fe {N (SiMe3) 2} 2] are reported. Computational studies …

Studies on the reactivity of complexes of the type [(η5-C5H5) Co (NHC)(olefin)] with internal
and terminal alkynes are presented. The half sandwich complexes [(η5-C5H5) Co (i …

Merging two topical themes in main-group chemistry, namely, cooperative bimetallics and
frustrated-Lewis-pair (FLP) activity, this Forum Article focuses on the cooperativity-induced …

Deprotonation of [IPrPh] I (1) with Co {N (SiMe3) 2} 2 readily affords the abnormal N-
heterocyclic carbene (aNHC) complex (aIPrPh) 2CoI2 (2)(aIPrPh= 1, 3-bis (2, 6-iPr2C6H3)-2 …

The reaction of [(IPr2Me2) 2FePh2] with PhC CPh furnished a three-coordinate iron (II)
dialkenyl complex,[(IPr2Me2) Fe (σ-CPh CPh2) 2](1, IPr2Me2= 1, 3-diisopropyl-4, 5 …