Complexes of diamagnetic cations with radical anion ligands - IOPscience This site uses
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Bis (imino) acenaphthenes (BIAN) have been known for many years. However, it is only
since the 1990s that such compounds have been recognized as robust ligands for the …

The reactivity of digallane (dpp-Bian) Ga–Ga (dpp-Bian)(1), which consists of redox-active
ligand 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene (dpp-Bian), has been studied …

Abstract α‐Diimine ligands have contributed extensively to the coordination chemistry of the
majority of the transition metals; bis (arylimino) acenaphthene ligands (BIANs) have been …

The reactions of monomeric [(dpp-Bian) M (thf) 4](M= Ca (1a), Sr (1b); dpp-Bian= 1, 2-bis [(2,
6-diisopropylphenyl) imino] acenaphthene) with 4, 4′-bipyridyl (4, 4′-bipy) proceed with …

Abstract Compounds [Sr (dpp‐bian)(thf) 4](2),[Ba (dpp‐bian)(dme) 2.5](3) and [Mg (dtb‐
bian)(thf) 2](4)(dpp‐bian= 1, 2‐bis [(2, 6‐diisopropylphenyl) imino] acenaphthene; dtb‐bian …

Although the chemistry of transition metal polyphosphide anions has attracted significant
attention, there are few reports of studies in which such species have been synthesized …

The diimine complexes with bulky fluorinated N‐substituents [NiII (FDAD) 2] 1 and [CoII
(FDAD) 2] 2 [FDAD= N, N′‐bis (pentafluorophenyl)‐2, 3‐dimethyl‐1, 4‐diaza‐1, 3 …

Aryl bis (imino) acenaphthenes (Ar-BIANs) are well-established rigid and sterically bulky
diimine ligands, which are redox-noninnocent and versatile π-acceptors due to their low …

Abstract The reduction of 2‐[(2, 6‐diisopropylphenyl) imino] acenaphthen‐1‐one (dpp‐
MIAN) with metallic calcium in THF affords tetrameric [(dpp‐MIAN) Ca (THF)] 4 (1). A further …