Design of collective motions from synthetic molecular switches, rotors, and motors

D Dattler, G Fuks, J Heiser, E Moulin, A Perrot… - Chemical …, 2019 - ACS Publications
Precise control over molecular movement is of fundamental and practical importance in
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …

[HTML][HTML] Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Towards artificial molecular factories from framework-embedded molecular machines

S Krause, BL Feringa - Nature Reviews Chemistry, 2020 - nature.com
Controlling cooperativity, synchronization, amplification and translation of intermolecular
and intramolecular dynamics over different length scales for applications in stimuli …

Sub-cycle atomic-scale forces coherently control a single-molecule switch

D Peller, LZ Kastner, T Buchner, C Roelcke, F Albrecht… - Nature, 2020 - nature.com
Scanning probe techniques can leverage atomically precise forces to sculpt matter at
surfaces, atom by atom. These forces have been applied quasi-statically to create surface …

Intra-and intermolecular self-assembly of a 20-nm-wide supramolecular hexagonal grid

Z Zhang, Y Li, B Song, Y Zhang, X Jiang, M Wang… - Nature …, 2020 - nature.com
For the past three decades, the coordination-driven self-assembly of three-dimensional
structures has undergone rapid progress; however, parallel efforts to create large discrete …

[HTML][HTML] How to control single-molecule rotation

GJ Simpson, V García-López, A Daniel Boese… - Nature …, 2019 - nature.com
The orientation of molecules is crucial in many chemical processes. Here, we report how
single dipolar molecules can be oriented with maximum precision using the electric field of a …

[HTML][HTML] The evolution of molecular machines through interfacial nanoarchitectonics: From toys to tools

K Ariga - Chemical Science, 2020 - pubs.rsc.org
Molecular machines are often regarded as molecular artworks and sometimes as fancy
molecular toys. However, many researchers strive to operate molecular machines as useful …

[HTML][HTML] A chiral molecular propeller designed for unidirectional rotations on a surface

Y Zhang, JP Calupitan, T Rojas, R Tumbleson… - Nature …, 2019 - nature.com
Synthetic molecular machines designed to operate on materials surfaces can convert
energy into motion and they may be useful to incorporate into solid state devices. Here, we …

Multi-functional switch effect in interlocking molecular rotators-on-graphene systems using electric fields

X Li, F Qi, R Zhao, Z Qiu, Y Li, M Long… - Journal of Materials …, 2022 - pubs.rsc.org
One approach to design electronic devices is to use molecules whose configuration can be
actively modified to control their electrical conductivity. A recent theoretical study provides a …

Molecular gears: from solution to surfaces

Y Gisbert, S Abid, C Kammerer… - Chemistry–A European …, 2021 - Wiley Online Library
This review highlights the major efforts devoted to the development of molecular gears over
the past 40 years, from pioneering covalent bis‐triptycyl systems undergoing intramolecular …