Metal‐free synthesis: Diamination of alkenes by using phenylhydrazine and
azodicarboxylates could be achieved in a one‐pot manner under very mild conditions (see …

We report the first demonstrations of intra-and intermolecular acyclic nitronate olefin
cycloaddition (ANOC) reactions that enable the highly efficient syntheses of isoxazolines …

O, ω‐Unsaturated N‐tosyl alkoxyamines undergo unexpected RhIII‐catalyzed
intramolecular cyclization by oxyamination to produce oxygen‐containing heterocycles …

The first visible light-induced dioxygenation of α, β-unsaturated amides with N-hydroxy
compounds under air was developed with the use of the non-toxic organic dye rose bengal …

Dioxygenation of olefins is a valuable synthetic tool for the construction of 1, 2‐diols and α‐
oxygenated ketones. The use of radical approaches to achieve this direct 1, 2 …

A highly efficient copper-catalyzed cyclization/cyanation cascade of unactivated olefins
bearing oximes is described. A variety of cyano-containing isoxazolines have been obtained …

A novel, selective and metal-free iminoxyl radical-promoted cascade oxyalkylation/
alkylarylation of unactivated alkenes and activated alkenes via tandem O–C/C–C/C–C bond …

A copper-catalyzed efficient and practical method has been developed for the synthesis of 1,
2-diketones and α-keto esters. TEMPO was used as a radical initiator and scavenger …

An efficient iron-catalyzed cyclization of ketoxime acetates with N, N-dimethylaniline for the
synthesis of symmetrical pyridines has been developed. A methyl carbon on N, N …

Cobalt complex Co (nmp) 2 can efficiently catalyze the aerobic oxidative 5-exo cyclization of
β, γ-unsaturated oximes to afford isoxazolines. The key cyclization step involves the …