Tale of the Breslow intermediate, a central player in N-heterocyclic carbene organocatalysis: then and now

M Pareek, Y Reddi, RB Sunoj - Chemical Science, 2021 - pubs.rsc.org
N-Heterocyclic carbenes (NHCs) belong to the popular family of organocatalysts used in a
wide range of reactions, including that for the synthesis of complex natural products and …

N-Heterocyclic carbene-catalyzed enantioselective (dynamic) kinetic resolutions and desymmetrizations

Y Zhang, H Cai, X Gan, Z Jin - Science China Chemistry, 2024 - Springer
N-heterocyclic carbene-catalyzed enantioselective kinetic resolutions, dynamic kinetic
resolutions, and desymmetrization reactions are systematically reviewed. The content is …

Radical NHC catalysis

K Liu, M Schwenzer, A Studer - ACS Catalysis, 2022 - ACS Publications
Radical/radical cross-coupling reactions represent an efficient and straightforward approach
for the construction of chemical bonds and accordingly have drawn increasing attention over …

Carbene-catalyzed chemoselective reaction of unsymmetric enedials for access to Furo [2, 3-b] pyrroles

G Fan, Q Wang, J Xu, P Zheng, YR Chi - Nature Communications, 2023 - nature.com
A carbene-catalyzed chemoselective reaction of unsymmetric enedials is disclosed. The
reaction provides a concise access to bicyclic furo [2, 3-b] pyrroles derivatives in excellent …

Catalytic, metal-free amide synthesis from aldehydes and imines enabled by a dual-catalyzed umpolung strategy under redox-neutral conditions

MS Liu, W Shu - ACS Catalysis, 2020 - ACS Publications
The synthesis of amides is a long-term theme in chemistry and related areas. The use of
readily available and cost-effective precursors for straightforward amide synthesis with atom …

Carboxylic acids as building blocks in catalytic asymmetric reactions

N Majumdar - ACS Catalysis, 2022 - ACS Publications
Catalytic asymmetric transformation is a powerful strategy for the introduction of chirality to
synthesize diverse nonracemic molecular entities. Chiral molecules play a significant role in …

Electroredox carbene organocatalysis with iodide as promoter

P Zhou, W Li, J Lan, T Zhu - Nature Communications, 2022 - nature.com
Oxidative carbene organocatalysis, inspired from Vitamin B1 catalyzed oxidative activation
from pyruvate to acetyl coenzyme A, have been developed as a versatile synthetic method …

Oxidative N‐Heterocyclic Carbene Catalysis

C De Risi, A Brandolese, G Di Carmine… - … A European Journal, 2023 - Wiley Online Library
N‐Heterocyclic carbene (NHC) catalysis is a by now consolidated organocatalytic platform
for a number of synthetic (asymmetric) transformations via diverse reaction …

NHC-catalyzed covalent activation of heteroatoms for enantioselective reactions

R Song, Z Jin, YR Chi - Chemical Science, 2021 - pubs.rsc.org
Covalent activation of heteroatoms enabled by N-heterocyclic carbene (NHC) organic
catalysts for enantioselective reactions is evaluated and summarized in this review. To date …

N-Heterocyclic carbene-based tetradentate platinum (ii) complexes for phosphorescent OLEDs with high brightness

G Li, S Liu, Y Sun, W Lou, YF Yang… - Journal of Materials …, 2022 - pubs.rsc.org
Organic light-emitting diode (OLED) is an attractive technology for display applications in
high-end electronics. Tetradentate Pt (II) complexes are phosphorescence emitters of great …