Electrochemical late-stage functionalization
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …
diversification of novel molecular entities with improved physicochemical or biological …
Electrophotocatalysis: combining light and electricity to catalyze reactions
H Huang, KA Steiniger, TH Lambert - Journal of the American …, 2022 - ACS Publications
Visible-light photocatalysis and electrocatalysis are two powerful strategies for the promotion
of chemical reactions that have received tremendous attention in recent years. In contrast …
of chemical reactions that have received tremendous attention in recent years. In contrast …
Photoelectrochemical asymmetric catalysis enables site-and enantioselective cyanation of benzylic C–H bonds
The enantioselective functionalization of ubiquitous C (sp 3)–H bonds is ideally suited for
the construction of three-dimensional chiral structures. However, organic molecules often …
the construction of three-dimensional chiral structures. However, organic molecules often …
Electrocatalysis as an enabling technology for organic synthesis
Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …
achieving challenging transformations at the forefront of synthetic organic chemistry …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
Photoelectrochemical asymmetric catalysis enables enantioselective heteroarylcyanation of alkenes via C–H functionalization
XL Lai, HC Xu - Journal of the American Chemical Society, 2023 - ACS Publications
The asymmetric difunctionalization of alkenes, a method transforming readily accessible
alkenes into enantioenriched chiral structures of high value, has long been a focal point of …
alkenes into enantioenriched chiral structures of high value, has long been a focal point of …
Photoelectrochemical asymmetric catalysis enables direct and enantioselective decarboxylative cyanation
XL Lai, M Chen, Y Wang, J Song… - Journal of the American …, 2022 - ACS Publications
The development of efficient and sustainable methods for decarboxylative transformations is
of great importance due to the ease of availability and nontoxicity of carboxylic acids …
of great importance due to the ease of availability and nontoxicity of carboxylic acids …
Synthetic molecular photoelectrochemistry: new frontiers in synthetic applications, mechanistic insights and scalability
S Wu, J Kaur, TA Karl, X Tian… - Angewandte Chemie …, 2022 - Wiley Online Library
Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …
the generation and handling of reactive intermediates. PEC permits selective single …
Ketyl radical coupling enabled by polycyclic aromatic hydrocarbon electrophotocatalysts
JM Edgecomb, SN Alektiar, NGW Cowper… - Journal of the …, 2023 - ACS Publications
Herein, we report a new class of electrophotocatalysts, polycyclic aromatic hydrocarbons,
that promote the reduction of unactivated carbonyl compounds to generate versatile ketyl …
that promote the reduction of unactivated carbonyl compounds to generate versatile ketyl …
Red light-based dual photoredox strategy resembling the Z-scheme of natural photosynthesis
Photoredox catalysis typically relies on the use of single chromophores, whereas strategies,
in which two different light absorbers are combined, are rare. In photosystems I and II of …
in which two different light absorbers are combined, are rare. In photosystems I and II of …