Understanding and controlling fluorinated diacyl peroxides and fluoroalkyl radicals in alkene fluoroalkylations
S Kawamura, M Sodeoka - The Chemical Record, 2023 - Wiley Online Library
The demand for practical methods for the synthesis of novel fluoroalkyl molecules is
increasing owing to their diverse applications. Our group has achieved efficient …
increasing owing to their diverse applications. Our group has achieved efficient …
Radical Reactions in Organic Synthesis: Exploring in-, on-, and with-Water Methods
C Chatgilialoglu, S Barata-Vallejo, T Gimisis - Molecules, 2024 - mdpi.com
Radical reactions in water or aqueous media are important for organic synthesis, realizing
high-yielding processes under non-toxic and environmentally friendly conditions. This …
high-yielding processes under non-toxic and environmentally friendly conditions. This …
C–F Activation of Fluorinated Esters Using Photocatalytically Generated Diaminoalkyl Radical
VS Kostromitin, AO Sorokin, VV Levin… - Organic Letters, 2023 - ACS Publications
A method for hydrofluoroalkylation of alkenes with trifluoroacetic esters under visible light
irradiation affording difluorinated products is described. The reaction involves readily …
irradiation affording difluorinated products is described. The reaction involves readily …
Silver-Promoted Three-Component Synthesis of Perfluoroalkenyl Pyrroles through Partial Defluorinative Functionalization of Perfluoroalkyl Halides
WJ Ji, W Han, YY Ren, M Ma, ZL Shen, XQ Chu - Organic Letters, 2024 - ACS Publications
A silver-promoted three-component heterocyclization of alkynes, perfluoroalkyl halides, and
1, 3-dinucleophiles was developed for the efficient synthesis of privileged (E) …
1, 3-dinucleophiles was developed for the efficient synthesis of privileged (E) …
Photodriven Radical Perfluoroalkylation–Thiolation of Unactivated Alkenes Enabled by Electron Donor–Acceptor Complex
L Liu, Q Wang, Y Li, M Liu, B Liu, Q Li, K Feng - Organic Letters, 2024 - ACS Publications
A clean and direct three-component radical 1, 2-difunctionalization of various alkenes with
perfluoroalkyl iodides and thiosulfonates enabled by the electron donor–acceptor complex …
perfluoroalkyl iodides and thiosulfonates enabled by the electron donor–acceptor complex …
Photoredox-catalyzed direct C–H monofluoromethylation of heteroarenes
N Ramkumar, K Plantus, M Ozola, A Mishnev… - New Journal of …, 2023 - pubs.rsc.org
Fluoroalkyl groups play a vital role in pharmaceutical products and agrochemicals, where
their installation onto aryl and heterocyclic rings can often lead to enhanced …
their installation onto aryl and heterocyclic rings can often lead to enhanced …
Visible-Light-Induced Domino Perfluoroalkylation/Cyclization to Access Perfluoroalkylated Quinazolinones by an EDA Complex
F Meng, Y Cui, W Xu, WC Yang - Organic Letters, 2024 - ACS Publications
The electron donor–acceptor (EDA) complexes have been extensively studied, which
formed an electronically excited state, obviating the need for an exogenous photocatalyst …
formed an electronically excited state, obviating the need for an exogenous photocatalyst …
Photoredox Activation of Fluorinated Organozinc Reagents: Hydrofluoroalkylation of Unactivated and Electron Deficient Alkenes
AA Gladkov, VV Levin, AD Dilman - The Journal of Organic …, 2024 - ACS Publications
Hydrofluoroalkylation of alkenes with organozinc reagents under photocatalytic conditions is
described. The fluorinated alkyl radicals were generated from organozincs by the single …
described. The fluorinated alkyl radicals were generated from organozincs by the single …
Visible Light-Induced Oxy-perfluoroalkylation of Olefins via Ternary Electron Donor–Acceptor Complexes
C Liu, Y Huo, J Bu, Z Yuan, K Liang… - The Journal of Organic …, 2024 - ACS Publications
Perfluoroalkyl iodides generally formed electron donor–acceptor (EDA) complexes by
halogen bonding with a nitrogen atom containing Lewis bases. Since the electronegativity of …
halogen bonding with a nitrogen atom containing Lewis bases. Since the electronegativity of …
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent
FY Zhou, JY Chen, L Jiao - Chem, 2024 - cell.com
The incorporation of perfluoroalkyl groups into molecules leads to unique properties, and
perfluoroalkylation reagents play a vital role. Although various types of perfluoroalkylation …
perfluoroalkylation reagents play a vital role. Although various types of perfluoroalkylation …