A new series of derivatives of 3-(1, 4-diazabicyclo [3.2. 2] nonan-4-yl) dibenzo [b, d]
thiophene 5, 5-dioxide with high binding affinities and selectivity for α7-nicotinic …

The use of atomic oxygen (O (3P)) as potent oxidant in water has suffered from the lack of a
facile, efficient source. The photodeoxygenation of aromatic sulfoxides to the corresponding …

Adenosine-5′-phosphosulfate kinase (APSK) catalyzes the phosphorylation of adenosine-
5′-phospho-sulfate (APS) to 3′-phospho-APS (PAPS). In plants, this enzymatic activity is …

Aromatic heterocyclic oxides, such as dibenzothiophene S-oxide (DBTO), have been
suggested to release ground state atomic oxygen [O (3P)] upon irradiation, and as such …

A protocol has been developed for direct Csp3–Csp2 bond formation at the 4-and 6-
positions of dibenzothiophenes using a gold (I) catalyst with terminal alkynes and …

Botulinum neurotoxins are the most toxic proteins currently known. Based on a recently
identified potent lead structure, 2, 4-dichlorocinnamic acid hydroxamate, herein we report on …

Photolysis of N-benzoyl-S, S-diphenylsulfilimine or N-benzoyl dibenzothiophene sulfilimine
produces PhNCO and also benzoylnitrene. Direct observation of the triplet nitrene, energetic …

Photoinduced deoxygenation of dibenzothiophene S-oxide (DBTO) has been suggested to
release atomic oxygen [O (3 P)]. To expand the conditions and applications where O (3 P) …

Photodeoxygenation of aryl sulfoxides, such as dibenzothiophene S-oxide (DBTO),
produces atomic oxygen [O (3P)] in solution. The mechanism of alkene oxidation with O (3P) …

CASSCF and multireference MP2 calculations were carried out on thiophene-S-oxide (TO)
and selenophene-Se-oxide (SeO), comparing the energies of the ground state to the first two …