MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Histidine as a key modulator of molecular self-assembly: Peptide-based supramolecular materials inspired by biological systems

Y Chen, K Tao, W Ji, VB Kumar, S Rencus-Lazar… - Materials Today, 2022 - Elsevier
Histidine, a versatile proteinogenic amino acid, plays a broad range of roles in all living
organisms and behaves as a key mediator of the interactions of biomolecules with inorganic …

Guest molecule-mediated energy harvesting in a conformationally sensitive peptide–metal organic framework

Y Chen, S Guerin, H Yuan, J O'Donnell… - Journal of the …, 2022 - ACS Publications
The apparent piezoelectricity of biological materials is not yet fully understood at the
molecular level. In particular, dynamic noncovalent interactions, such as host–guest binding …

Metal‐Organic Frameworks for Gene Therapy and Detection

Y He, D Li, L Wu, X Yin, X Zhang… - Advanced Functional …, 2023 - Wiley Online Library
Gene therapy holds great promise as a biomedicine for treating cancer, viral infection, and
recessive gene disorders, while genetic detection has been used for disease diagnosis and …

Artificial metal–peptide assemblies: bioinspired assembly of peptides and metals through space and across length scales

J Dong, Y Liu, Y Cui - Journal of the American Chemical Society, 2021 - ACS Publications
The exploration of chiral crystalline porous materials, such as metal–organic complexes
(MOCs) or metal–organic frameworks (MOFs), has been one of the most exciting recent …

Integrating Computation, Experiment, and Machine Learning in the Design of Peptide‐Based Supramolecular Materials and Systems

M Ramakrishnan, A van Teijlingen… - Angewandte Chemie …, 2023 - Wiley Online Library
Interest in peptide‐based supramolecular materials has grown extensively since the 1980s
and the application of computational methods has paralleled this. These methods contribute …

Noncovalent peptide assembly enables crystalline, permutable, and reactive thiol frameworks

SS Hess, F Coppola, VT Dang, PN Tran… - Journal of the …, 2023 - ACS Publications
Though thiols are exceptionally versatile, their high reactivity has also hindered the
synthesis and characterization of well-defined thiol-containing porous materials. Leveraging …

Recent progress of metal-organic framework-based photodynamic therapy for cancer treatment

Y Ye, Y Zhao, Y Sun, J Cao - International Journal of …, 2022 - Taylor & Francis
Photodynamic therapy (PDT), combining photosensitizers (PSs) and excitation light at a
specific wavelength to produce toxic reactive oxygen species, has been a novel and …

Exploring helical peptides and foldamers for the design of metal helix frameworks: current trends and future perspectives

N Bajpayee, T Vijayakanth, S Rencus‐Lazar… - Angewandte …, 2023 - Wiley Online Library
Flexible and biocompatible metal peptide frameworks (MPFs) derived from short and ultra‐
short peptides have been explored for the storage of greenhouse gases, molecular …

Assembly of π-stacking helical peptides into a porous and multivariable proteomimetic framework

SL Heinz-Kunert, A Pandya, VT Dang… - Journal of the …, 2022 - ACS Publications
The evolution of proteins from simpler, self-assembled peptides provides a powerful
blueprint for the design of complex synthetic materials. Previously, peptide–metal …