Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Being mono-aza analogues of sulfoxides and sulfones, sulfimides and sulfoximines,
respectively, are important compounds in asymmetric synthesis, crop protection and …

Direct construction of chiral S (VI) from prochiral S (II) is a formidable challenge due to the
inevitable formation of stable chiral S (IV). Previous synthetic strategies rely on the …

N–N linkages are found in many natural compounds and endow fascinating structural and
functional properties. In comparison to the myriad methods for the construction of C–N …

Sulfur can form diverse S (IV) and S (VI) stereogenic centers, of which some have gained
significant attention recently due to their increasing use as pharmacophores in drug …

Sulfur–heteroatom bonds such as S–S and S–N are found in a variety of natural products
and often play important roles in biological processes. Despite their widespread …

In this work, we developed a metal-free and redox-neutral strategy for the selective S-
alkylation of sulfenamides under basic conditions to yield sulfilimines. The key step involves …

Sulfoximines have gained considerable recognition as an important structural motif in drug
discovery of late. In particular, the clinical kinase inhibitors for the treatment of cancer …

Direct synthesis of NH-sulfoximines from sulfides has been achieved through O and NH
transfer in the same reaction, occurring with complete selectivity. The reaction is mediated …

In this investigation, an unprecedented transition-metal-free and redox-neutral synthesis of
sulfilimines was realized through the S-arylation of readily obtainable sulfenamides …