Organic carbonates as solvents in synthesis and catalysis

B Schaffner, F Schaffner, SP Verevkin… - Chemical …, 2010 - ACS Publications
A solvent is one key component in a chemical transformation. As a reaction medium it
controls the interactions between reaction partners through heat transfer and intermolecular …

[图书][B] Hydrolases in organic synthesis: regio-and stereoselective biotransformations

UT Bornscheuer, RJ Kazlauskas - 2006 - books.google.com
From reviews to the first edtion:" Bornscheuer and Kazlauskas have set out, and succeeded,
in producing a definitive manual on hydrolytic enzymes (especially lipases, esterases, and …

Asymmetric Catalysis with CO2:  Direct Synthesis of Optically Active Propylene Carbonate from Racemic Epoxides

XB Lu, B Liang, YJ Zhang, YZ Tian… - Journal of the …, 2004 - ACS Publications
Asymmetric Catalysis with CO2: Direct Synthesis of Optically Active Propylene Carbonate from
Racemic Epoxides | Journal of the American Chemical Society ACS ACS Publications C&EN …

Bifunctional Aluminum Catalyst for CO2 Fixation: Regioselective Ring Opening of Three-Membered Heterocyclic Compounds

WM Ren, Y Liu, XB Lu - The Journal of Organic Chemistry, 2014 - ACS Publications
Regioselective ring opening of three-membered heterocyclic compounds (epoxides or N-
substituted aziridines) at various temperatures was observed in coupling reactions with CO2 …

Catalytic asymmetric addition of carbon dioxide to propylene oxide with unprecedented enantioselectivity

A Berkessel, M Brandenburg - Organic Letters, 2006 - ACS Publications
New chiral catalyst systems were developed for the reaction of carbon dioxide with
propylene oxide (PO) at atmospheric pressure to generate enantiomerically enriched …

Synthesis of Cyclic Carbonates Catalyzed by CaI2–Et3N and Studies on Their Biocatalytic Kinetic Resolution

C Terazzi, K Laatz, J von Langermann… - ACS Sustainable …, 2022 - ACS Publications
Herein, we report a simple catalytic system consisting of CaI2 in combination with Et3N as a
ligand for the efficient cycloaddition of CO2 to a variety of epoxides. Terminal (bio-based) …

Catalytic Asymmetric Cycloaddition of Carbon Dioxide and Propylene Oxide Using Novel Chiral Polymers of BINOL‐Salen‐Cobalt (III) Salts

P Yan, H Jing - Advanced Synthesis & Catalysis, 2009 - Wiley Online Library
Four new chiral polymers of BINOL‐Salen‐cobalt (III) salt complexes have been designed,
synthesized and applied to the direct fabrication of chiral propylene carbonate from racemic …

Role of the co-catalyst in the asymmetric coupling of racemic epoxides with CO 2 using multichiral Co (III) complexes: Product selectivity and enantioselectivity

WM Ren, GP Wu, F Lin, JY Jiang, C Liu, Y Luo… - Chemical …, 2012 - pubs.rsc.org
The kinetic resolution of racemic terminal epoxides with CO2 as reagent via enantioselective
coupling represents an attractive method for affording enantiopure epoxides and optically …

Re(CO)5Br-Catalyzed Coupling of Epoxides with CO2 Affording Cyclic Carbonates under Solvent-Free Conditions

JL Jiang, F Gao, R Hua, X Qiu - The Journal of organic chemistry, 2005 - ACS Publications
Re(CO)5Br-Catalyzed Coupling of Epoxides with CO2 Affording Cyclic Carbonates under
Solvent-Free Conditions | The Journal of Organic Chemistry ACS ACS Publications C&EN CAS …

Efficient catalytic synthesis of optically active cyclic carbonates via coupling reaction of epoxides and carbon dioxide

SW Chen, RB Kawthekar, GJ Kim - Tetrahedron letters, 2007 - Elsevier
Chiral Co (salen) complexes bearing the Lewis acid of group 13 can efficiently catalyze the
reactions of carbon dioxide with epoxides in the presence of catalytic amounts of alkali metal …