Syntheses, structures, and magnetic properties of discrete cyano-bridged heterodinuclear complexes composed of MnIII (salen)-type complex and MIII (CN) 6 anion …

R Ishikawa, M Nakano, BK Breedlove, M Yamashita - Polyhedron, 2013 - Elsevier
Abstract Reacting [Mn III (5-TMAM (R)-salmen)(H 2 O) 2](ClO 4) 3· H 2 O with [M III (CN) 6]
3− moieties yields a series of discrete cyano-bridged heterodinuclear complexes,[Mn III (5 …

Structure–property trends in cyanido-bridged tetranuclear FeIII/NiII single-molecule magnets

YZ Zhang, UP Mallik, R Clérac, NP Rath, SM Holmes - Polyhedron, 2013 - Elsevier
Treatment of [NEt4][(Tp∗ Me) FeIII (CN) 3]· H2O with nickel (II) trifluoromethanesulfonate
affords {[(Tp∗ Me) FeIII (CN) 3] 2 [NiII (DMF) 4] 2 [OTf] 2}· 2DMF (1) while {[(Tp∗ Me) FeIII …

Composition dependence of magnetic relaxation for Co IIx Ni II1− x chain-based compounds with mixed double azide–tetrazolate bridges

M Cheng, YS Ding, EQ Gao, Z Zhang, QX Jia - Dalton Transactions, 2016 - pubs.rsc.org
Seven isomorphous 2D CoIIxNiII1− x (0≤ x≤ 1) compounds based on ferromagnetic chains
with mixed double [(μ-EO-N3)(μ-N–N-tetrazolate)](EO= end-on) were synthesized and then …

Controlled Synthesis of Heterotrimetallic Single‐Chain Magnets from Anisotropic High‐Spin 3 d–4 f Nodes and Paramagnetic Spacers

MX Yao, Q Zheng, K Qian, Y Song… - … –A European Journal, 2013 - Wiley Online Library
By using the node‐and‐spacer approach in suitable solvents, four new heterotrimetallic 1D
chain‐like compounds (that is, containing 3d–3d′–4f metal ions),{[Ni (L) Ln (NO3) 2 (H2O) …

Single‐Chain Magnets

KS Pedersen, A Vindigni, R Sessoli… - Molecular Magnetic …, 2017 - Wiley Online Library
In this chapter, we review the basic theory for the characterization of one‐dimensional
magnetic materials exhibiting magnetic bistability, the so‐called single‐chain magnets …

Redox effects of low-spin Ru (II/III) on slow magnetic relaxation of Ru–Mn (III) 1D cyanide-bridged complexes

X Zhu, S Su, W Cao, Y Wen, S Hu, X Wu… - Dalton Transactions, 2017 - pubs.rsc.org
A new one-dimensional cyanide-bridged complex [MnIII (salphen) RuII (DMAP) 4 (CN)
2](PF6)(1) and its oxidized derivative [MnIII (salphen) RuIII (DMAP) 4 (CN) 2](PF6) 2 (2) have …

A cyanido-bridged trinuclear {FeIII2NiII} complex decorated with organic radicals

YZ Zhang, DF Li, R Clérac, SM Holmes - Polyhedron, 2013 - Elsevier
Reaction of [NEt4][(pzTp) FeIII (CN) 3], nickel (II) trifluoromethanesulfonate and 4, 4, 5, 5-
tetramethylimidazoline-1-oxyl-2-(2′-pyridyl)(IM-2Py) affords {[(pzTp) FeIII (CN) 3] 2NiII (IM …

Synthesis, crystal structure and magnetic properties of H 2 tppz [ReCl 6] and [Cu (bpzm) 2 (μ-Cl) ReCl 3 (μ-ox) Cu (bpzm) 2 (μ-ox) ReCl 3 (μ-Cl)] n

I Gryca, J Palion-Gazda, B Machura, M Penkala… - Dalton …, 2015 - pubs.rsc.org
Two new Re (IV) compounds of formulae H2tppz [ReCl6](1) and [Cu (bpzm) 2 (μ-Cl) ReCl3
(μ-ox) Cu (bpzm) 2 (μ-ox) ReCl3 (μ-Cl)] n (2)[tppz= 2, 3, 5, 6-tetrakis (2-pyridyl) pyrazine and …

Two three-dimensional [Mo III (CN) 7] 4−-based magnets showing new topologies and ferrimagnetic ordering below 80 K

XQ Wei, KJ Wang, DQ Wu, D Shao, L Shi… - Dalton …, 2019 - pubs.rsc.org
The rational design and synthesis of heptacyanomolybdate-based magnets remain a
challenge due to the complexity of this system. Here, we reported the crystal structures and …

含钴钠混合金属的一维链配合物的合成及其结构

王会生, 潘志权 - 武汉工程大学学报, 2013 - cqvip.com
由于单链磁体在信息储存设备, 量子计算机及磁冰箱等方面的潜在应用, 对该领域的研究仍然
受到国内外科学家的重视. 为了提高它的能垒以便能够付诸应用, 需要选择适当的多齿螯合配体 …