Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

Fatty acids and their derivatives as renewable platform molecules for the chemical industry

U Biermann, UT Bornscheuer… - Angewandte Chemie …, 2021 - Wiley Online Library
Oils and fats of vegetable and animal origin remain an important renewable feedstock for the
chemical industry. Their industrial use has increased during the last 10 years from 31 to 51 …

Photoexcited nitroarenes for the oxidative cleavage of alkenes

A Ruffoni, C Hampton, M Simonetti, D Leonori - Nature, 2022 - nature.com
The oxidative cleavage of alkenes is an integral process that converts feedstock materials
into high-value synthetic intermediates,–. The most viable method to achieve this in one …

Cleavage of carbon–carbon bonds by radical reactions

P Sivaguru, Z Wang, G Zanoni, X Bi - Chemical Society Reviews, 2019 - pubs.rsc.org
In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …

Production of fuels and chemicals from biomass: condensation reactions and beyond

L Wu, T Moteki, AA Gokhale, DW Flaherty, FD Toste - Chem, 2016 - cell.com
Renewable resources and bio-based feedstocks may present a sustainable alternative to
petrochemical sources to satisfy modern society's ever-increasing demand for energy and …

Sustainable productions of organic acids and their derivatives from biomass via selective oxidative cleavage of C–C bond

M Wang, J Ma, H Liu, N Luo, Z Zhao, F Wang - ACS Catalysis, 2018 - ACS Publications
Biomass is renewable and the most abundant carbon resource, and it shows great potential
for sustainable production of chemicals in the future. With respect to limited fossil reserves …

Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2

A Gonzalez-de-Castro, J Xiao - Journal of the American Chemical …, 2015 - ACS Publications
A mild and operationally simple iron-catalyzed protocol for the selective aerobic oxidation of
aromatic olefins to carbonyl compounds is described. Catalyzed by a Fe (III) species bearing …

Prospects and challenges for nitrogen-atom transfer catalysis

MN Cosio, DC Powers - Nature Reviews Chemistry, 2023 - nature.com
Conversion of C–H bonds to C–N bonds via C–H amination promises to streamline the
synthesis of nitrogen-containing compounds. Nitrogen-group transfer (NGT) from metal …

Hydrogen peroxide as an oxidant in biomass-to-chemical processes of industrial interest

SP Teong, X Li, Y Zhang - Green Chemistry, 2019 - pubs.rsc.org
Production of chemicals and fuels from renewable biomass is a hot topic of current research.
Theoretically, most of the fuels and chemicals from petroleum resources can be synthesised …

Recent advances in sustainable production and catalytic transformations of fatty acid methyl esters

AS Belousov, AL Esipovich, EA Kanakov… - Sustainable Energy & …, 2021 - pubs.rsc.org
Green chemistry provides a broad range of possibilities for researchers to design products
and processes that minimise or eliminate the use and generation of hazardous substances …