Fullerenes in biology and medicine

E Castro, AH Garcia, G Zavala… - Journal of Materials …, 2017 - pubs.rsc.org
Fullerenes and related carbon based derivatives have shown a growing relevance in
biology and medicine, mainly due to the unique electronic and structural properties that …

Molecular and ionic diffusion in ion exchange membranes and biological systems (Cells and proteins) studied by NMR

VI Volkov, AV Chernyak, IA Avilova, NA Slesarenko… - Membranes, 2021 - mdpi.com
The results of NMR, and especially pulsed field gradient NMR (PFG NMR) investigations,
are summarized. Pulsed field gradient NMR technique makes it possible to investigate …

Regioselective Synthesis and Crystallographic Characterization of Nontethered cis-1 and cis-2 Bis(benzofuro)[60]fullerene Derivatives

L Ding, B Jin, Z Guo, Y Zhao, J Chen, R Peng - Organic letters, 2019 - ACS Publications
The regioselective synthesis of fullerene bis-adducts remains challenging because it
produces large amounts of regioisomers. Novel nontethered cis-1 and cis-2 bis …

Facile synthesis of C 60-nano materials and their application in high-performance water splitting electrocatalysis

O Fernandez-Delgado, AR Puente-Santiago… - Sustainable Energy & …, 2020 - pubs.rsc.org
Here, we report the synthesis and characterization of crystalline C60 nanomaterials and
their applications as bifunctional water splitting catalysts. The shapes of the resulting …

Diversion of the Arbuzov reaction: alkylation of C–Cl instead of phosphonic ester formation on the fullerene cage

AK Ol'ga, AS Peregudov, SI Troyanov… - Organic & …, 2019 - pubs.rsc.org
We report an “inversed” Arbuzov reaction of the fullerene derivatives C60Ar5Cl with trialkyl
phosphites P (OR) 3 producing alkylated fullerene derivatives C60Ar5R (R= Me, Et, iPr, nBu) …

Halogenated fullerenes as precursors for the synthesis of functional derivatives of C60 and C70

EA Khakina, PA Troshin - Russian Chemical Reviews, 2017 - iopscience.iop.org
The review is devoted to the use of halogenated fullerenes as precursors for the synthesis of
functional derivatives of fullerenes C 60 and C 70. Data on chemical transformations of …

Exploring exohedral functionalization of fullerene with automation and Neural Network Potential

M Liu, Y Han, Y Cheng, X Zhao, H Zheng - Carbon, 2023 - Elsevier
Exohedral functionalized fullerenes have shown superior physicochemical properties over
pristine carbon cages. The functional groups could significantly improve solubility, electron …

Synthesis, characterization and anti-HIV activity of polycarboxylic [60] fullerene derivatives obtained in the reaction of C60Cl6 with a hydroquinone ether

II Voronov, VM Martynenko, AV Chernyak, I Godovikov… - Tetrahedron letters, 2020 - Elsevier
We report the preparation and characterization of five new [60] fullerene derivatives formed
in the novel reaction of C 60 Cl 6 with dimethyl 2, 2′-(1, 4-phenylenebis-(oxy)) diacetate …

Fullerene stabilizer 4, 11, 15, 30-tetraarylamino fullerenoarylaziridine: regioselective synthesis, crystallographic characterization derivatives, and potential application …

Z Chai, L Luo, B Jin, Y Zhao, L Xiao, G Li… - ACS Applied Energy …, 2020 - ACS Publications
The safe storage of propellants has become increasingly challenging because of extreme
storage and operational environments. Hence, high-performance stabilizers should be …

Self-Organization of Fullerene Derivatives in Solutions and Biological Cells Studied by Pulsed Field Gradient NMR

IA Avilova, AV Chernyak, YV Soldatova… - International Journal of …, 2022 - mdpi.com
Fullerene derivatives are of great interest in various fields of science and technology.
Fullerene derivatives are known to have pronounced anticancer and antiviral activity. They …