Synergistic dual dynamic bonds in covalent adaptable networks

J Zhao, Z Zhang, C Wang, X Yan - CCS Chemistry, 2024 - chinesechemsoc.org
Covalent adaptable networks (CANs), comprising polymer networks crosslinked by dynamic
covalent bonds (DCBs), have garnered considerable attention as sustainable materials …

High-performance recyclable and malleable epoxy resin with vanillin-based hyperbranched epoxy resin containing dual dynamic bonds

Y Hao, L Zhong, T Li, J Zhang… - … Sustainable Chemistry & …, 2023 - ACS Publications
Dynamic covalent polymer networks represent new opportunities in the design of
sustainable epoxy resins due to their excellent malleability and reprocessability; however …

High-strength and multi-recyclable epoxy vitrimer containing dual-dynamic covalent bonds based on the disulfide and imine bond metathesis

C Luo, W Wang, W Yang, X Liu, J Lin… - ACS Sustainable …, 2023 - ACS Publications
Epoxy (EP) vitrimers are currently regarded as ideal substitutes for traditional thermosetting
resins, as this class of materials combines the advantages of thermoplastic and thermoset …

[HTML][HTML] Photocurable extended vanillin-based resin for mechanically and chemically recyclable, self-healable and digital light processing 3D printable thermosets

A Liguori, S Subramaniyan, JG Yao… - European Polymer …, 2022 - Elsevier
A vanillin-based photocurable resin was designed for circularity by incorporation of imine
functionalities through a Schiff-base reaction between the aldehyde function of vanillin and …

Synthesis, Recycling and High‐Throughput Reprocessing of Phase‐Separated Vitrimer‐Thermoplastic Blends

LMA Joosten, P Cassagnau… - Advanced Functional …, 2024 - Wiley Online Library
Phase‐separated polymer blends including a transesterification vitrimer and polypropylene
are synthesized from widely available precursors through reactive processing. It is shown …

Masked primary amines for a controlled plastic flow of vitrimers

F Van Lijsebetten, K De Bruycker, JM Winne… - ACS macro …, 2022 - ACS Publications
We present a simple method for increasing the reprocessability of vinylogous urethane (VU)
vitrimers while decreasing the possibility of creep deformation at lower temperatures. In …

Dual‐Dynamic Chemistries‐Based Fast‐Reprocessing and High‐Performance Covalent Adaptable Networks

K Hu, B Wang, X Xu, Y Su, W Zhang… - Macromolecular …, 2023 - Wiley Online Library
Covalent adaptable networks (CANs) possess multiple functions including reprocessing (or
recyclability), self‐healing, welding, shape shifting, 3D printing, etc., due to the network …

Fast‐Reprocessing, Postadjustable, Self‐Healing Covalent Adaptable Networks with Schiff Base and Diels–Alder Adduct

X Xu, S Ma, S Wang, B Wang, H Feng… - Macromolecular …, 2022 - Wiley Online Library
Covalent adaptable networks (CANs) are a new type of polymers, which possess excellent
performance of thermosets and reprocessability of thermoplastics. Nevertheless, it is still a …

Raman Spectroscopy Reveals Phase Separation in Imine-Based Covalent Adaptable Networks

SK Schoustra, MHP de Heer Kloots, J Posthuma… - …, 2022 - ACS Publications
The introduction of dynamic covalent bonds into cross-linked polymer networks enables the
development of strong and tough materials that can still be recycled or repurposed in a …

Recyclable vitrimer epoxy coatings for durable protection

F Van Lijsebetten, S Engelen, E Bauters… - European Polymer …, 2022 - Elsevier
In this research, the synthesis and application of vitrimer epoxy coatings for long-term
corrosion protection of metal surfaces are described. To that end, a polyamine curing agent …