C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

The functionalization of C–H bonds has created new approaches to preparing organic
molecules by enabling new strategic “disconnections” during the planning of a synthetic …

C–H functionalization has become widely recognized as an exciting new strategy for the
synthesis of complex molecular targets. Instead of relying on functional groups as the …

This Perspective presents the fundamental principles, the elementary reactions, the initial
catalytic systems, and the contemporary catalysts that have converted C–H bond …

The construction of carbon–carbon bonds is a central tenet of modern synthetic chemistry.
Metal-catalyzed C–H functionalization can serve as a particularly powerful tool for achieving …

Sulfoximines are increasingly incorporated in agrochemicals and pharmaceuticals, with the
two enantiomers of chiral sulfoximines often having profoundly different binding interactions …

The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

Donor/donor carbenes are relatively new in the field of carbene chemistry; although
applications in C− H and X− H insertion reactions are few in number, they demonstrate …

The laboratory synthesis of complex organic molecules relies heavily on the introduction
and manipulation of functional groups, such as carbon–oxygen or carbon–halogen bonds; …

This tutorial review presents a description of the controlling elements of intermolecular C–H
functionalization by means of C–H insertion by donor/acceptor rhodium carbenes. These …