Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered
the systems of choice in homogeneous catalysis due to their stable metal–ligand framework …

The catalytic addition of water to unsaturated C–C or C–N π bonds represent one of the
most important and environmentally sustainable methods to form C–O bonds for the …

Magnetic stir bars are routinely used by every chemist doing synthetic or catalytic
transformations in solution. Each bar lasts for months or years, as the regular PTFE …

The mercury test is a rapid and widely used method for distinguishing truly homogeneous
molecular catalysis from nanoparticle metal catalysis. In the current work, using various M0 …

We have developed a new dialkylbiaryl monophosphine ligand, GPhos, that supports a
palladium catalyst capable of promoting carbon–nitrogen cross-coupling reactions between …

We report the arene hydrogenation of ethers, amides, and esters at room temperature and
low hydrogen pressure, starting from [(CAAC) Rh (COD) Cl](CAAC= cyclic alkyl amino …

Actual palladium catalysts in synthetic transformations in reaction mixtures are usually
represented by dynamic catalytic systems that contain various interconvertible forms of metal …

Reversible leaching of palladium nanoparticles occurs in a variety of catalytic reactions
including cross-couplings, amination, the Heck reaction, etc. It is complemented by capturing …

Complexes of palladium and nickel with N-heterocyclic carbene ligands (M/NHC, M= Pd, Ni)
are widely used as effective catalysts for various amination reactions. A previously …

Imidazolium salts have found ubiquitous applications as N-heterocyclic carbene precursors
and metal nanoparticle stabilizers in catalysis and metallodrug research. Substituents …