Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

JM Frost, KLM Harriman, M Murugesu - Chemical science, 2016 - pubs.rsc.org
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

The role of anharmonic phonons in under-barrier spin relaxation of single molecule magnets

A Lunghi, F Totti, R Sessoli, S Sanvito - Nature communications, 2017 - nature.com
The use of single molecule magnets in mainstream electronics requires their magnetic
moment to be stable over long times. One can achieve such a goal by designing compounds …

Two-coordinate Co (II) imido complexes as outstanding single-molecule magnets

XN Yao, JZ Du, YQ Zhang, XB Leng… - Journal of the …, 2017 - ACS Publications
The pursuit of single-molecule magnets (SMMs) with better performance urges new
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …

The regulation research of topology and magnetic exchange models of CPs through Co (II) concentration adjustment

X Dong, Z Shi, D Li, Y Li, N An, Y Shang… - Journal of Solid State …, 2023 - Elsevier
We have designed and synthesized two new Co-CPs by modulating the concentration of
cobalt ions, namely [Co 3 (HL) 2 (4, 4′-bibp) 3 (H 2 O) 4] n (1) and {[Co 9 (L) 4 (4, 4′-bibp) …

A four-coordinate cobalt (II) single-ion magnet with coercivity and a very high energy barrier

Y Rechkemmer, FD Breitgoff, M Van Der Meer… - Nature …, 2016 - nature.com
Single-molecule magnets display magnetic bistability of molecular origin, which may one
day be exploited in magnetic data storage devices. Recently it was realised that increasing …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets

S Mondal, A Lunghi - Journal of the American Chemical Society, 2022 - ACS Publications
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …

Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets

A Sarkar, S Dey, G Rajaraman - Chemistry–A European …, 2020 - Wiley Online Library
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …