Organic synthesis using nitroxides

D Leifert, A Studer - Chemical Reviews, 2023 - ACS Publications
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Homogeneous oxidative transformations mediated by copper catalyst systems

L Marais, HCM Vosloo, AJ Swarts - Coordination Chemistry Reviews, 2021 - Elsevier
Oxidative transformations involve the conversion of organic substrates, through various
processes to obtain oxygenates such as alcohols, phenolic and carbonyl compounds which …

Efficient Selective Oxidation of Aromatic Alkanes by Double Cobalt Active Sites over Oxygen Vacancy‐rich Mesoporous Co3O4

Y Liu, Y Zheng, D Feng, L Zhang, L Zhang… - Angewandte …, 2023 - Wiley Online Library
The development of efficient catalyst for selective oxidation of hydrocarbon to functional
compounds remains a challenge. Herein, mesoporous Co3O4 (mCo3O4‐350) showed …

Persistent Radical Tetrathiafulvalene‐Based 2D Metal‐Organic Frameworks and Their Application in Efficient Photothermal Conversion

J Su, N Xu, R Murase, ZM Yang… - Angewandte …, 2021 - Wiley Online Library
A series of stable radical 2D metal‐organic frameworks has been assembled.(m‐TTFTB) 3
(m‐Tetrathiafulvalene‐tetrabenzoate) trimer building blocks are beneficial for the stability of …

Novel Z-scheme Sr2MgSi2O7: Eu2+, Dy3+/Ag3PO4 photocatalyst for round-the-clock efficient degradation of organic pollutants and hydrogen production

J Tang, X Liu, Y Liu, X Zhang, Y Lin, L Chen… - Chemical Engineering …, 2022 - Elsevier
The photocatalytic reaction can carry out only under light irradiation, which limits the
application of photocatalytic technology in the wastewater treatment and hydrogen …

The golden touch by light: A finely engineered luminogen empowering high photoactivatable and photodynamic efficiency for cancer phototheranostics

X Chen, N Niu, D Li, Z Zhang, Z Zhuang… - Advanced Functional …, 2023 - Wiley Online Library
Photoactivatable agent is a powerful tool in biomedicine studies due to high‐precision
spatiotemporal control of light. However, those previously reported agents generally suffer …

An intramolecular macrocyclase in plant ribosomal peptide biosynthesis

LS Mydy, J Hungerford, DN Chigumba… - Nature chemical …, 2024 - nature.com
The biosynthetic dogma of ribosomally synthesized and posttranslationally modified
peptides (RiPP) involves enzymatic intermolecular modification of core peptide motifs in …

Unsymmetrical relay C–H alkenylation and [2+ 2] cycloaddition of N-arylsydnones with allenyl acetates leading to quinoline-fused cyclobutanes

X Song, K Wang, X Zhang, X Fan - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
In spite of the prevalence of fused cyclobutane skeletons in natural products and
pharmaceuticals, synthetic strategies for their assembly from simple starting materials still …

Fabrication of loaded Ag sensitized round-the-clock highly active Z-scheme BiFeO3/Ag/Sr2MgSi2O7: Eu2+, Dy3+/Ag photocatalyst for metronidazole degradation and …

J Tang, Y Liu, X Zhang, Y Tian, T Jin, D Fang… - Journal of Power …, 2023 - Elsevier
To achieve efficient round-the-clock photocatalytic degradation of organic pollutants with
simultaneous hydrogen production, Sr 2 MgSi 2 O 7: Eu 2+, Dy 3+ with long-afterglow …

Role of TEMPO in enhancing permanganate oxidation toward organic contaminants

H Zhang, Z Shi, R Bai, D Wang, F Cui… - Environmental …, 2021 - ACS Publications
Permanganate (Mn (VII)) has been widely applied as an oxidant in water treatment plants.
However, compared with ozone, Fenton, and other advanced oxidation processes, the …