[HTML][HTML] Rigid multipodal platforms for metal surfaces

M Valášek, M Lindner, M Mayor - Beilstein journal of …, 2016 - beilstein-journals.org
In this review the recent progress in molecular platforms that form rigid and well-defined
contact to a metal surface are discussed. Most of the presented examples have at least three …

Modular bidentate hybrid NHC‐thioether ligands for the stabilization of palladium nanoparticles in various solvents

A Rühling, K Schaepe, L Rakers… - Angewandte Chemie …, 2016 - Wiley Online Library
The synthesis of four different bidentate hybrid NHC‐thioether ligands is presented. The
corresponding palladium nanoparticles are stable in various solvents, depending on the …

Porous honeycomb self-assembled monolayers: Tripodal adsorption and hidden chirality of carboxylate anchored triptycenes on Ag

S Das, G Nascimbeni, RO De La Morena, F Ishiwari… - ACS …, 2021 - ACS Publications
Molecules with tripodal anchoring to substrates represent a versatile platform for the
fabrication of robust self-assembled monolayers (SAMs), complementing the conventional …

Single-Molecule Observation of Redox Reactions Enabled by Rigid and Isolated Tripodal Molecules

Y Kobayashi, Y Yokota, RA Wong, M Hong… - The Journal of …, 2022 - ACS Publications
Tracking various chemical reactions, including electrochemical and photochemical reactions
at the single-molecule level, is expected to yield a great deal of knowledge from both …

Cyano-Substituted Triptycene-Based Monolayers on Au (111): Tripodal Adsorption, Dipole Engineering, and Charge Transfer

S Das, A Asyuda, Y Shoji, A Kosaka… - The Journal of …, 2021 - ACS Publications
Molecules with tripodal anchoring groups are generally capable of forming self-assembled
monolayers (SAMs), which, however, frequently suffer from inhomogeneous bonding …

Spatial and lateral control of functionality by rigid molecular platforms

M Valášek, M Mayor - Chemistry–A European Journal, 2017 - Wiley Online Library
Surface mounted molecular devices have received significant attention in the scientific
community because of their unique ability to construct functional materials. The key involves …

Synthesis of molecular tripods based on a rigid 9, 9′-spirobifluorene scaffold

M Valasek, K Edelmann, L Gerhard… - The Journal of …, 2014 - ACS Publications
The efficient synthesis of a new tripodal platform based on a rigid 9, 9′-spirobifluorene with
three acetyl protected thiol groups in the positions 2, 3′ and 6′ for deposition on Au (111) …

Triptycene-Based Tripodal Self-Assembled Monolayer on Indium Tin Oxide

S Das, F Ishiwari, Y Shoji, T Fukushima… - The Journal of …, 2023 - ACS Publications
The monomolecular assembly of 1, 8, 13-tricarboxytriptycene (Trip-CA) on a test oxide
substrate, represented by indium tin oxide (ITO), was studied. For this purpose, X-ray …

Ideal redox behavior of the high-density self-assembled monolayer of a molecular tripod on a Au (111) surface with a terminal ferrocene group

T Kitagawa, H Matsubara, K Komatsu, K Hirai… - Langmuir, 2013 - ACS Publications
A dyad consisting of a tripod-shaped trithiol with an adamantane core and a terminal
ferrocenyl group linked through ap-phenyleneethynylene bridge was synthesized. The …

Zwitterionic dithiocarboxylates derived from N-heterocyclic carbenes: coordination to gold surfaces

U Siemeling, H Memczak, C Bruhn, F Vogel… - Dalton …, 2012 - pubs.rsc.org
The zwitterionic dithiocarboxylates 1+–CS2−–4+–CS2− were prepared by reacting the
corresponding N-heterocyclic carbenes 1, 3-bis (2, 6-diisoproylphenyl) imidazol-2-ylidene …