Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

Room-temperature logic-in-memory operations in single-metallofullerene devices

J Li, S Hou, YR Yao, C Zhang, Q Wu, HC Wang… - Nature materials, 2022 - nature.com
In-memory computing provides an opportunity to meet the growing demands of large data-
driven applications such as machine learning, by colocating logic operations and data …

Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets

S Mondal, A Lunghi - Journal of the American Chemical Society, 2022 - ACS Publications
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …

Quantitative theory of magnetic interactions in solids

A Szilva, Y Kvashnin, EA Stepanov, L Nordström… - Reviews of Modern …, 2023 - APS
This review addresses the method of explicit calculations of interatomic exchange
interactions of magnetic materials. This involves exchange mechanisms normally referred to …

Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes

R Jankowski, M Wyczesany, S Chorazy - Chemical Communications, 2023 - pubs.rsc.org
Multifunctional materials, which exhibit diverse physical properties, are candidates for the
new generation of smart devices that realize many tasks simultaneously. Particular attention …

Toward exact predictions of spin-phonon relaxation times: An ab initio implementation of open quantum systems theory

A Lunghi - Science Advances, 2022 - science.org
Spin-phonon coupling is the main driver of spin relaxation and decoherence in solid-state
semiconductors at finite temperature. Controlling this interaction is a central problem for …

[HTML][HTML] Magnetic molecules on surfaces: SMMs and beyond

G Gabarró-Riera, G Aromí, EC Sañudo - Coordination Chemistry Reviews, 2023 - Elsevier
In this critical review we cover the state of the art of surface deposition of complex magnetic
molecules. Deposition methods are reviewed, as well as the most used types of surfaces …

Recent advances in polyoxometalate-based single-molecule magnets

ZX Yang, F Gong, D Lin, Y Huo - Coordination Chemistry Reviews, 2023 - Elsevier
Single-molecule magnets (SMMs) have attracted increasing attention in recent years due to
the potentially applicable in high-density information storage and spintronic devices. There …

Large easy-axis magnetic anisotropy in a series of trigonal prismatic mononuclear cobalt (II) complexes with zero-field hidden single-molecule magnet behaviour: the …

A Landart-Gereka, MM Quesada-Moreno… - Inorganic Chemistry …, 2022 - pubs.rsc.org
The complexes [Co (L)] X· S (X= CoCl42−, S= CH3CN (1); X= ZnCl42−, S= CH3OH (2)),[Co
(L)] X2· S (X= ClO4−, S= 2CH3OH (3) and X= BF4−(4)) and [Co (L)(NCS) 2](5), where L= the …