In situ spectroscopic insights into the redox and acid-base properties of ceria catalysts

X Wang, M Li, Z Wu - Chinese Journal of Catalysis, 2021 - Elsevier
Cerium oxide (ceria) plays an important and fascinating role in heterogeneous catalysis as
illustrated by its versatile use as a catalyst, a catalyst support, or a promotor in various …

Two polymorphic polyoxometalate-based metal–organic frameworks for the efficient synthesis of functionalized sulfoxides and detoxification of mustard gas simulants

Y Chen, S Chang, H An, Y Li, Q Zhu… - ACS Sustainable …, 2021 - ACS Publications
The development of high-efficient catalysts for the oxidation reaction of sulfides received
much attention in recent years due to the extensive applications of such reactions from the …

Metal–organic framework-and polyoxometalate-based sorbents for the uptake and destruction of chemical warfare agents

TG Grissom, AM Plonka, CH Sharp… - … applied materials & …, 2020 - ACS Publications
The threat of chemical warfare agents (CWAs), assured by their ease of synthesis and
effectiveness as a terrorizing weapon, will persist long after the once-tremendous stockpiles …

Assessing Hydrolysis Performance of Ce(OH)4@PIM-1 Composites Functionalized with Amidoxime, Aldoxime, and Carboxylate Groups Toward Dimethyl 4 …

PO Aina, SK Mondal, AA Rownaghi… - ACS Applied Polymer …, 2024 - ACS Publications
In recent years, significant attention has been directed toward evaluating the reactivity of
diverse polymers to gauge their catalytic activity against hazardous chemicals. Among these …

Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO2

T Li, R Tsyshevsky, L Algrim, M McEntee… - … Applied Materials & …, 2021 - ACS Publications
The increased risk of chemical warfare agent usage around the world has intensified the
search for high-surface-area materials that can strongly adsorb and actively decompose …

A continuous flow generator of organic hypochlorites for the neutralization of chemical warfare agent simulants

VEH Kassin, DV Silva-Brenes, T Bernard, J Legros… - Green …, 2022 - pubs.rsc.org
Herein, we report the development of a continuous flow generator that produces highly
reactive organic hypochlorites for the chemical neutralization of sulfur-based chemical …

Capture and decomposition of the nerve agent simulant, DMCP, using the zeolitic imidazolate framework (ZIF-8)

AM Ebrahim, AM Plonka, N Rui, S Hwang… - … Applied Materials & …, 2020 - ACS Publications
Understanding mechanisms of decontamination of chemical warfare agents (CWA) is an
area of intense research aimed at developing new filtration materials to protect soldiers and …

NiCr2O4 nanozyme based portable sensor kit for on-site quantification of nerve agent mimic for environment monitoring

M Kumar, N Kaur, N Singh - Sensors and Actuators B: Chemical, 2023 - Elsevier
Nerve agents are among the most dangerous chemical known to the human being. On
account of an incident by utilizing nerve agents, the fabrication of a cost-effective and ready …

[HTML][HTML] Adsorptive degradation of dimethyl methylphosphonate over Zr-based metal–organic framework built from 3, 3′, 5, 5′-azobenzenetetracarboxylic acid

SK Chitale, YS Ko, JW Choi, JW Yoon, D Jo… - Journal of Hazardous …, 2022 - Elsevier
Chemical warfare agents (CWAs) pose a significant threat to humans because of their high
toxicity. Zirconium-based metal–organic frameworks (Zr-MOFs) are promising candidates for …

A computational study of water in UiO‐66 Zr‐MOFs: Diffusion, hydrogen bonding network, and confinement effect

S Wang, G Zhou, Y Sun, L Huang - AIChE Journal, 2021 - Wiley Online Library
For chemical warfare agent removal, the humidity emerges as an unavoidable challenge
that significantly affects the performance of metal–organic frameworks. In this work, via …