Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Small molecules such as H2, N2, CO, NH3, O2 are ubiquitous stable species and their
activation and role in the formation of value-added products are of fundamental importance …

Photocatalysis is believed to be one of the best methods to realize sustainable H 2
production. However, achieving this through heterogeneous photocatalysis still remains a …

Two major energy-related problems confront the world in the next 50 years. First, increased
worldwide competition for gradually depleting fossil fuel reserves (derived from past …

The pursuit of solar fuels has motivated extensive research on molecular electrocatalysts
capable of evolving hydrogen from protic solutions, reducing CO2, and oxidizing water …

Molecular electrocatalysts can play an important role in energy storage and utilization
reactions needed for intermittent renewable energy sources. This manuscript describes …

One of the most appealing strategies to address the problems of global warming and energy
shortage is to develop clean and sustainable energy source. To this end, considerable …

1. INTRODUCTION “The additional potential (beyond the thermodynamic requirement)
needed to drive a reaction at a certain rate is called the overpotential.” 1 Over the past …

A series of nickel bis (chelate) complexes having square planar coordination are studied for
light-driven and electrocatalytic hydrogen production from water. The complexes Ni (abt) 2 …