Carbon–Carbon Bond Cleavage for Late-Stage Functionalization
YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …
Photoexcited nitroarenes for the oxidative cleavage of alkenes
The oxidative cleavage of alkenes is an integral process that converts feedstock materials
into high-value synthetic intermediates,–. The most viable method to achieve this in one …
into high-value synthetic intermediates,–. The most viable method to achieve this in one …
Nitrogen dioxide catalyzed aerobic oxidative cleavage of C (OH)–C bonds of secondary alcohols to produce acids
Stable organic nitroxyl radicals are an important class of catalysts for oxidation reactions, but
their wide applications are hindered by their steric hinderance, high cost, complex operation …
their wide applications are hindered by their steric hinderance, high cost, complex operation …
Selective oxidation of alkenes to carbonyls under mild conditions
J Xu, Y Zhang, X Yue, J Huo, D Xiong, P Zhang - Green Chemistry, 2021 - pubs.rsc.org
Herein, a practical and sustainable method for the synthesis of aldehydes, ketones, and
carboxylic acids from an inexpensive olefinic feedstock is described. This transformation …
carboxylic acids from an inexpensive olefinic feedstock is described. This transformation …
Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst
Z Huang, R Guan, M Shanmugam… - Journal of the …, 2021 - ACS Publications
The oxidative cleavage of C═ C double bonds with molecular oxygen to produce carbonyl
compounds is an important transformation in chemical and pharmaceutical synthesis. In …
compounds is an important transformation in chemical and pharmaceutical synthesis. In …
Photochemical organocatalytic aerobic cleavage of C═ C bonds enabled by charge-transfer complex formation
YX Chen, JT He, MC Wu, ZL Liu, K Tang, PJ Xia… - Organic …, 2022 - ACS Publications
A novel visible-light-driven organocatalytic protocol to access aerobic oxidative cleavage of
olefins, promoted by sodium benzene sulfinate, is described herein. An array of alkenes …
olefins, promoted by sodium benzene sulfinate, is described herein. An array of alkenes …
Bis (methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O 2 under metal-and base-free conditions
KJ Liu, S Jiang, LH Lu, LL Tang, SS Tang, HS Tang… - Green …, 2018 - pubs.rsc.org
We describe an eco-friendly, practical and operationally simple procedure for the bis
(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic …
(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic …
Switchable Synthesis of Aryl Sulfones and Sulfoxides through Solvent-Promoted Oxidation of Sulfides with O2/Air
Z Cheng, P Sun, A Tang, W Jin, C Liu - Organic letters, 2019 - ACS Publications
A practical and switchable method for the synthesis of aryl sulfones and sulfoxides via
sulfide oxidation was developed. The chemoselectivities of products were simply controlled …
sulfide oxidation was developed. The chemoselectivities of products were simply controlled …
Scalable electrochemical aerobic oxygenation of indoles to isatins without electron transfer mediators by merging with an oxygen reduction reaction
W Zhuang, J Zhang, C Ma, JS Wright, X Zhang… - Organic …, 2022 - ACS Publications
An approach to electrochemical oxygenation of indoles leading to isatins was developed by
merging with a complementary cathode oxygen reduction reaction. The features of this …
merging with a complementary cathode oxygen reduction reaction. The features of this …
Photocatalytic carboxylation of styrenes with CO2 via C= C double bond cleavage
KG Cao, TY Gao, LL Liao, CK Ran, YX Jiang… - Chinese Journal of …, 2024 - Elsevier
Catalytic cleavage of C= C double bonds in alkenes is highly important to convert feedstocks
into high-value compounds. However, these approaches are mainly limited to oxidative …
into high-value compounds. However, these approaches are mainly limited to oxidative …