Stable Ln-MOFs as multi-responsive photoluminescence sensors for the sensitive sensing of Fe 3+, Cr 2 O 7 2−, and nitrofuran

L Duan, C Zhang, P Cen, X Jin, C Liang, J Yang… - …, 2020 - pubs.rsc.org
Two families of lanthanide (III) metal–organic frameworks (Ln-MOFs) constructed from a 2-(4-
pyridyl)-terephthalic acid (H2pta) ligand, namely [Ln4 (pta) 5 (Hpta) 2 (H2O) 4]· xH2O (1-Eu …

Highly selective and sensitive detection towards cationic Cu2+ and Fe3+ contaminants via an In-MOF based dual-responsive fluorescence probe

BB Guan, Q Li, YT Xu, LH Chen, ZS Wu, ZL Fan… - Inorganic Chemistry …, 2020 - Elsevier
Effective recognition and detection of heavy metal Cu 2+ and Fe 3+ ions from water are
highly desirable because of their serious harms to human health and environmental safety …

A series of lanthanide (III) metal–organic frameworks derived from a pyridyl-dicarboxylate ligand: single-molecule magnet behaviour and luminescence properties

C Zhang, X Ma, P Cen, X Jin, J Yang, YQ Zhang… - Dalton …, 2020 - pubs.rsc.org
The reactions of LnIII ions with a versatile pyridyl-decorated dicarboxylic acid ligand lead to
the formation of a series of novel three-dimensional (3D) Ln-MOFs,[Ln3 (pta) 4 (Hpta)(H2O)] …

Switching of easy-axis to easy-plane anisotropy in cobalt (II) complexes

Y Wu, J Xi, T Xiao, J Ferrando-Soria… - Inorganic Chemistry …, 2021 - pubs.rsc.org
A tetranuclear cubane-type complex [Co4 (ntfa) 4 (CH3O) 4 (CH3OH) 4](1) with a {Co4O4}
core, and a mononuclear complex [Co (ntfa) 2 (CH3OH) 2](2) have been rationally obtained …

Geometrical control of the magnetic anisotropy in six coordinate cobalt complexes

MR Saber, MK Singh, KR Dunbar - Chemical Communications, 2020 - pubs.rsc.org
The geometry of cobalt (II) ions in the axially distorted octahedral cation in [Co (MeCN)
6](BF4) 2 (1) was compared to the trigonal prismatic cation in [CoTppy] PF6 (2) which …

[HTML][HTML] Tuning magnetic anisotropy by the π-bonding features of the axial ligands and the electronic effects of gold (I) atoms in 2D {Co (L) 2 [Au (CN) 2] 2} n metal …

MA Palacios, IF Díaz-Ortega, H Nojiri… - Inorganic Chemistry …, 2020 - pubs.rsc.org
The assembly of a Co (II) salt with two [Au (CN) 2]− anions and ancillary ligands L afforded
2D complexes of the general formula {Co (L) 2 [Au (CN) 2] 2} n (where L= DMSO (1), DMF …

Lanthanide metal–organic frameworks assembled from unexplored imidazolylcarboxylic acid: structure and field-induced two-step magnetic relaxation

Y Wu, Y Zhou, S Cao, P Cen, YQ Zhang… - Inorganic …, 2020 - ACS Publications
A series of 3D homologous metal–organic frameworks,[M (H0. 5L) 2][M= Dy (1), Ho (2), Yb
(3), Sm (4), Gd (5), and Y (6); H2L= 5-(1 H-imidazol-1-yl) isophthalic acid], were isolated. In …

Magnetic investigations of monocrystalline [Co (NCS) 2 (L) 2] n: new insights into single-chain relaxations

M Ceglarska, M Böhme, T Neumann, W Plass… - Physical Chemistry …, 2021 - pubs.rsc.org
A large single crystal of a compound from the family of coordination polymer [Co (NCS) 2 (L)
2] n chains was synthesized and its magnetic properties are reported.[Co (NCS) 2 (4-(3 …

Enhancing single-molecule magnet behaviour through decorating terminal ligands in Dy 2 compounds

X Ma, B Chen, YQ Zhang, J Yang, Q Shi, Y Ma… - Dalton …, 2019 - pubs.rsc.org
The utilization of two isomorphic ligands with different substituents leads to two
centrosymmetric DyIII dimers, namely,[Dy2 (bfbpen) 2 (H2O) 2]· 2I−(1) and [Dy2 (bcbpen) 2 …

Tuning the coordination geometry and magnetic relaxation of Co (II) single-ion magnets by varying the ligand substitutions

G Peng, YF Qian, ZW Wang, Y Chen… - Crystal Growth & …, 2021 - ACS Publications
Three mononuclear Co (II) complexes with the formulas of [Co (L1) 2](1),[Co (L2) 2 (CH3OH)
2](2), and [Co (L3) 2 (CH3OH) 2](3)(HL1= 4-nitro-2-((E)-(propylimino) methyl) phenol, HL2 …