Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry

JP Sutter, V Béreau, V Jubault, K Bretosh… - Chemical Society …, 2022 - pubs.rsc.org
The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …

Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Heterometallic supramolecular polymers: From synthesis to properties and applications

MK Bera, S Sarmah, DC Santra, M Higuchi - Coordination Chemistry …, 2024 - Elsevier
Heterometallic supramolecular polymers (HMSPs) comprising two or more heterometal ions
have drawn significant research interest in the last two decades because of their attractive …

SMM behavior tuned by an exchange coupling LEGO approach for chimeric compounds: first 2p–3d–4f Heterotrispin complexes with different metal ions bridged by …

AA Patrascu, M Briganti, S Soriano… - Inorganic …, 2019 - ACS Publications
Coordination compounds containing three different spin carriers (2p, 3d, and 4f), with the
general formula [MIIDyIII (LH)(hfac) 5](M= Co, Ni, Mn, Zn), have been obtained using …

Modulation of single-chain magnet behaviour in a heterometallic Fe 2 Co cyanide-bridged 2D sheet

R Kharel, J Yadav, S Konar - Chemical Communications, 2024 - pubs.rsc.org
A cyanide-bridged Fe2Co 2D sheet exhibiting electron transfer coupled spin transition
(ETCST) with co-existence of magnetic ordering below 50 K is reported. The complex …

[HTML][HTML] Advancement in the synthesis of metal complexes with special emphasis on Schiff base ligands and their important biological aspects

P Singh, P Yadav, KK Sodhi, A Tomer, SB Mehta - Results in Chemistry, 2024 - Elsevier
Schiff bases and their metal complexes are versatile compounds synthesized from the
condensation of an amino compound with carbonyl compound and widely used for the …

Enhanced Single‐Chain Magnet Behavior via Anisotropic Exchange in a Cyano‐Bridged MoIII–MnII Chain

L Shi, D Shao, XQ Wei, KR Dunbar… - Angewandte Chemie …, 2020 - Wiley Online Library
Anisotropic magnetic exchange is of great value for the design of high performance
molecular nanomagnets. In the present work, enhanced single‐chain magnet (SCM) …

Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe2Cu3] Subunits

J Yang, ML You, S Liu, YF Deng, XY Chang… - Inorganic …, 2023 - ACS Publications
Extending a selected cyanometalate block into a higher dimensional framework continues to
present intriguing challenges in the fields of chemistry and material science. Here, we …

[HTML][HTML] Heteroleptic trivalent chromium in coordination chemistry: Novel building blocks for addressing old challenges in multimetallic luminescent complexes

JR Jiménez, B Doistau, M Poncet, C Piguet - Coordination Chemistry …, 2021 - Elsevier
Although less famous than low-spin trivalent cobalt found in [Co III (NH 3) 6− x Cl x] Cl 3− x
(x≤ 3), which was exploited by Alfred Werner during the early part of the 20th century for …

Improved single-chain-magnet behavior in a biradical-based nitronyl nitroxide-Cu–Dy chain

J Xie, HD Li, M Yang, J Sun, LC Li… - Chemical …, 2019 - pubs.rsc.org
Improved single-chain-magnet behavior in a biradical-based nitronyl nitroxide-Cu–Dy chain
- Chemical Communications (RSC Publishing) DOI:10.1039/C9CC00570F Royal Society of …